I think the correct answer from the choices listed above is option 1. It would be the molecule carbon disulphide that will be polar, based on the structure of the choices given. Hope this answers the question. Have a nice day. Feel free to ask more questions.
Answer:

The air in the atmosphere consists of nitrogen, oxygen, which is the life-sustaining substance for animals and humans, carbon dioxide, water vapour and small amounts of other elements (argon, neon, etc.). Higher in the atmosphere air also contains ozone, helium and hydrogen.
A large volume of material will have a small amount of mass when the
material in question is gaseous or porous, and therefore has a lot of
space within it despite taking up a large amount of space overall.