Suppose you had an organic molecule such as cystine, and you chemically removed the --nh2 group and replaced it with --cooh. Dra
w the structural formula for this molecule and speculate about its chemical properties. Is the central carbon asymmetric before the change? After?
1 answer:
Cystine is dimer of Cystein amino acid formed by oxidation reaction. Its main function is to provide mechanical strength to proteins and allow them to retain their 3-D structures and also serves as a substrate for the cystine-glutamate antiporter.
As shown in figure cystine has two amino groups (highlighted blue) and two carboxylic groups (highlighted green). In its original structure cystine is neutral in nature as it has equal number of basic (NH₂) and acidic (COOH) moieties along with two chiral centers (asymmetric carbons) highlighted with red spots.
When one -NH₂ group is replaced by -COOH group the cystine is converted into an acidic compound with three COOH groups and a NH₂ group. Also, one asymmetric carbon will convert into a symmetrical carbon with a loss of one chiral carbon.
In second step, when another NH₂ is replaced by COOH, the acidic strength of resulting compound will increase along with conversion of last chiral carbon into symmetric carbon.
Therefore, the final structure will be acidic in nature with zero chiral carbons as shown in figure attached below.
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Answer:
Very dense.
Explanation:
Conceptually, you are taking a large amount of atoms and putting them into a small container. This means the spaces between atoms has to be smaller and the substance is more dense. (see image)
Mathematically, the equation for density is mass divided by volume ( ). If you divide a big number by a small number, you still have a pretty big number (ex 4/2=2 versus 6/1=6)
