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Dimas [21]
2 years ago
7

What is the lowest unoccupied molecular orbital in F2?

Chemistry
1 answer:
Juliette [100K]2 years ago
7 0

Answer:

σ*2pₓ, also called 3\sigma_{u}\text{*}

Explanation:

I have drawn the MO diagram for fluorine below.

Each F atom contributes seven valence electrons, so we fill the MOs of fluorine with 14 electrons.

We have filled the \pi \text{*2p}_{y} and \pi \text{*2p}_{z} MOs.

They are the highest occupied molecular orbitals (HOMOs).

The next unfilled level (the LUMO) is the σ*2pₓ orbital. If you use the symmetry notation, it is called the 3\sigma_{u}\text{*} orbital.

This is the orbital that fluorine uses when it acts as an electron acceptor.

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