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expeople1 [14]
3 years ago
12

What is the density of carbon dioxide gas at -25.2°C and 98.0 kPa? A. 0.232 g/L OB. 0.279 g/L OC. 0.994 g/L OD. 1.74 g/L O E. 2.

09 g/L
Chemistry
1 answer:
Black_prince [1.1K]3 years ago
8 0

Answer:

E. 2.09\frac{g}{L}

Explanation:

From the ideal gasses equation we have:

PV=nRT

where P is the pressure, V is the volume, n is the number of moles, R is the gas constant, and T is the temperature.

The number of moles is also expressed as: n=\frac{mass}{Molar mass}

If replacing this in the ideal gasses equation we have:

PV=\frac{mass}{Molarmass}.RT

If we pass V to divide, we have:

P=\frac{mass}{V}.\frac{RT}{Molarmass}

And the density d = \frac{mass}{V}, so replacing, we have:

P=\frac{dRT}{M}

Solving for d, we have:

d=\frac{P.M}{R.T}

Now we have to be sure that we have the correct units, so we need to convert the units for pressure and temperature:

-Convert P=98kPa to atm

98.0kPa*\frac{0.00986923atm}{1kPa}=0.97atm

-Convert T=-25.2°C to K

-25.2^{o}C+273.15=247.95K

Finally we can replace the values in the equation:

d=\frac{(0.97atm)*(44.01\frac{g}{mol})}{(0.082\frac{atm.L}{mol.K})*(247.15K)}

d=2.09\frac{g}{L}

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Find how many milliliters of NaOH should be used to reach the half-equivalence point during the titration of 20.00 mL 0.888 M bu
Varvara68 [4.7K]

<u>Answer:</u> The volume of NaOH solution required to reach the half-equivalence point is 0.09 mL

<u>Explanation:</u>

The chemical equation for the dissociation of butanoic acid follows:

CH_3CH_2CH_2COOH\rightleftharpoons CH_3CH_2CH_2COO^-+H^+

The expression of K_a for above equation follows:

K_a=\frac{[CH_3CH_2CH_2COO^-][H^+]}{[CH_3CH_2CH_2COOH]}

We are given:

[CH_3CH_2CH_2COOH]=0.888M\\K_a=1.54\times 10^{-5}

[CH_3CH_2CH_2COO^-]=[H^+]

Putting values in above expression, we get:

1.54\times 10^{-5}=\frac{[H^+]^2}{0.888}

[H^+]=-0.0037,0.0037

Neglecting the negative value because concentration cannot be negative

To calculate the volume of base, we use the equation given by neutralization reaction:

n_1M_1V_1=n_2M_2V_2

where,

n_1,M_1\text{ and }V_1 are the n-factor, molarity and volume of acid which is butanoic acid

n_2,M_2\text{ and }V_2 are the n-factor, molarity and volume of base which is NaOH.

We are given:

n_1=1\\M_1=\frac{0.0037}{2}M\text{ (half equivalence)}\\V_1=20.00mL\\n_2=1\\M_2=0.425M\\V_2=?mL

Putting values in above equation, we get:

1\times \frac{0.0037}{2}\times 20.00=1\times 0.425\times V_2\\\\V_2=\frac{1\times 0.0037\times 20}{1\times 0.425\times 2}=0.087mL

Hence, the volume of NaOH solution required to reach the half-equivalence point is 0.09 mL

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Answer:

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