All the conversions have a net value of 1
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Answer:
-5.51 kJ/mol
Explanation:
Step 1: Calculate the heat required to heat the water.
We use the following expression.

where,
- c: specific heat capacity
- m: mass
- ΔT: change in the temperature
The average density of water is 1 g/mL, so 75.0 mL ≅ 75.0 g.

Step 2: Calculate the heat released by the methane
According to the law of conservation of energy, the sum of the heat released by the combustion of methane (Qc) and the heat absorbed by the water (Qw) is zero
Qc + Qw = 0
Qc = -Qw = -22.0 kJ
Step 3: Calculate the molar heat of combustion of methane.
The molar mass of methane is 16.04 g/mol. We use this data to find the molar heat of combustion of methane, considering that 22.0 kJ are released by the combustion of 64.00 g of methane.

Can you say please? Just kidding!
The process of science discovery depends upon changing your theories based upons new evidence from new experiments. New technology allows for new experiments, leading to new theories.
The given equation from the problem above is already balance,
N2O5 ---> 2NO2 + 0.5O2
Since, in every mole of N2O5 consumed, 2 moles of NO2 are formed, we can answer the problem by multiplying the given rate, 7.81 mol/L.s with the ratio.
(7.81 mol/L.s) x (2 moles NO2 formed/ 1 mole of N2O5 consumed)
= 15.62 mol/L.s
The answer is the rate of formation of NO2 is approximately 15.62 mol/L.s.