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IRISSAK [1]
3 years ago
14

What happens when the vapor pressure of a liquid is equal to the external pressure? The liquid freezes The intermolecular forces

become stronger in the liquid The liquid boils Dispersion forces become weaker in the liquid An equilibrium exists between the liquid and the solid state.
Chemistry
1 answer:
Makovka662 [10]3 years ago
6 0

Answer:

The liquid boils.

Explanation:

Vapor pressure is simply defined as the pressure exerted on a substance (solid/liquid) by the vapor of the substance collected just at the top of the surface of the substance. In concise words, it is the pressure of Vapor that is in contact with its solid or liquid state.

For a liquid, it is the pressure of the Vapor gathering at the top of the surface of the liquid.

When this Vapor pressure matches the external pressure, the temperature stays constant and the molecules of the liquid all through the liquid can gain enough energy, rise to the surface of the liquid and break free in gaseous form; thereby, boiling.

The definition of boiling point basically explains that it is the point at which temperature stays constant, and the vapour pressure of the liquid matches the atmospheric/external pressure around the liquid and its liquid molecules change into vapor.

This is why liquids boil faster at higher altitudes; the atmospheric pressure at higher altitudes is reduced, hence, the temperature at which liquid boils at this high altitude is normally lower than its known boiling point temperature.

It is also why food cooks to a temperature higher than the boiling point of water in a pressure cooker/pot. The added pressure ensures that the cooking water boils at temperatures higher than its boiling point; thereby exposing the cooking ingredients to a higher temperature, leading to faster cooking.

Hence, it is obvious why boiling is the answer to this question.

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What is the vapor pressure of the solution if 35.0 g of water is dissolved in 100.0 g of ethyl alcohol at 25 ∘C? The vapor press
masya89 [10]

<u>Answer:</u> The vapor pressure of the solution is 43.55 mmHg

<u>Explanation:</u>

To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}      .....(1)

  • <u>For water:</u>

Given mass of water = 35.0 g

Molar mass of water = 18 g/mol

Putting values in equation 1, we get:

\text{Moles of water}=\frac{35.0g}{18g/mol}=1.944mol

  • <u>For ethyl alcohol:</u>

Given mass of ethyl alcohol = 100.0 g

Molar mass of ethyl alcohol = 46 g/mol

Putting values in equation 1, we get:

\text{Moles of ethyl alcohol}=\frac{100.0g}{46g/mol}=2.174mol

Total moles of solution = [1.944 = 2.174] moles = 4.118 moles

  • Mole fraction of a substance is given by:

\chi_A=\frac{n_A}{n_A+n_B}

<u>For water:</u>

\chi_{\text{water}}=\frac{n_{\text{water}}}{n_{\text{water}}+n_{\text{ethyl alcohol}}}

\chi_{water}=\frac{1.944}{4.118}=0.472

<u>For ethyl alcohol:</u>

\chi_{\text{ethyl alcohol}}=\frac{n_{\text{ethyl alcohol}}}{n_{\text{water}}+n_{\text{ethyl alcohol}}}

\chi_{\text{ethyl alcohol}}=\frac{2.174}{4.118}=0.528

Dalton's law of partial pressure states that the total pressure of the system is equal to the sum of partial pressure of each component present in it.

To calculate the vapor pressure of the solution, we use the law given by Dalton, which is:

P_T=\sum_{i=1}^n (p_i\times \chi_i)

Or,

P_T=[(p_{\text{water}}\times \chi_{\text{water}})+(p_{\text{ethyl alcohol}}\times \chi_{\text{ethyl alcohol}}

We are given:

Vapor pressure of water = 23.8 mmHg

Vapor pressure of ethyl alcohol = 61.2 mmHg

Putting values in above equation, we get:

p_T=[(23.8\times 0.472)+(61.2\times 0.528)]\\\\p_T=43.55mmHg

Hence, the vapor pressure of the solution is 43.55 mmHg

4 0
3 years ago
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