Innovated Understanding Curious Logical
First, we have to remember the molarity formula:

Part 1:
In this case, our solute is sodium nitrate (NaNO3), and we have the mass dissolved in water, then we have to convert grams to moles. For that, we need the molecular weight:

Then, we calculate the moles present in the solution:

Now, we have the necessary data to calculate the molarity (with the solution volume of 200 mL):

The molarity of this solution equals 0.2339 M.
Part 2:
In this case, we have the same amount (in moles and mass) of sodium nitrate, but a different volume of solution, then we only have to change it:

So, the molarity of this solution is 0.1701 M.
Two steps by inspection 1 qt = 0.25 gallons, 13.6 g/mL = 13.6 kg/L
0.25 gallon x 3.785411784 L/gallon x 13.6 kg/L x 1 lb/0.45359237 kg = 28.374 lb.
Hope this Helps!
Answer:
A !!
it a mix where everything is combined together
Heat of vaporization of water will be required as water is already at it's boiling point thus heat required will be 540*10=5400 cal