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pentagon [3]
3 years ago
13

The dissolution of 0.200 l of sulfur dioxide at 19 °c and 745 mmhg in water yields 500.0 ml of aqueous sulfurous acid. The solut

ion is titrated with 13.4 ml of sodium hydroxide. What is the molarity of naoh?
Chemistry
1 answer:
aivan3 [116]3 years ago
8 0

Answer:

Molarity=1.22\ M

Explanation:

Given:  

Pressure = 745 mm Hg

Also, P (mm Hg) = P (atm) / 760

Pressure = 745 / 760 = 0.9803 atm

Temperature = 19 °C

The conversion of T( °C) to T(K) is shown below:

T(K) = T( °C) + 273.15  

So,  

T₁ = (19 + 273.15) K = 292.15 K  

Volume = 0.200 L

Using ideal gas equation as:

PV=nRT

where,  

P is the pressure

V is the volume

n is the number of moles

T is the temperature  

R is Gas constant having value = 0.0821 L.atm/K.mol

Applying the equation as:

0.9803 atm × 0.200 L = n × 0.0821 L.atm/K.mol × 292.15 K  

⇒n = 0.008174 moles

From the reaction shown below:-

H_2SO_3+2NaOH\rightarrow Na_2SO_3+2H_2O

1 mole of H_2SO_4 react with 2 moles of NaOH

0.008174 mole of H_2SO_4 react with 2*0.008174 moles of NaOH

Moles of NaOH = 0.016348 moles

Volume = 13.4 mL = 0.0134 L ( 1 mL = 0.001 L)

So,

Molarity=\frac{Moles\ of\ solute}{Volume\ of\ the\ solution}

Molarity=\frac{0.016348}{0.0134}\ M

Molarity=1.22\ M

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Aliun [14]

Answer:

Option 3 is correct.

The atomic nucleus of each element has a unique number of protons. Therefore, the energy of the electron layers of the atoms of each element is unique.

If we have the energy released from each electron transfer between the layers of the atom, we can identify the element.

4 0
2 years ago
The bromination of acetone is acid-catalyzed.CH3COCH3 + Br2 CH3COCH2Br + H+ + Br -The rate of disappearance of bromine was measu
Ann [662]

Answer:

a) The rate law is:

rate = k[Acetone][Br₂]⁰[H⁺] = k[Acetone][H⁺]

b) The value of k is:

k = 3.86 × 10⁻³ M⁻¹ · s⁻¹

Explanation:

Acetone (M) Br2 (M) H+ (M) Rate (M/s)

0.30                 0.050 0.050 5.7 x 10-5

0.30                   0.10 0.050 5.7 x 10-5

0.30                  0.050    0.10       1.2 x 10-4

0.40              0.050  0.20  3.1 x 10-4

0.40               0.050         0.050 7.6 x 10-5

A generic rate law for this reaction could be written as follows:

rate = k[Acetone]ᵃ[Br₂]ᵇ[H⁺]ⁿ

The rate for the reaction in trial 2 is:

rate 2 = 5.7 ×10⁻⁵M/s = k(0.3)ᵃ(0.1)ᵇ(0.050)ⁿ

For the reaction in trial 1:

rate 1 = 5.7 ×10⁻⁵M/s = k(0.3)ᵃ(0.050)ᵇ(0.050)ⁿ

If we divide both expressions, we can obtain "b": rate2 / rate1:

rate2/rate1 = k(0.3)ᵃ(0.1)ᵇ(0.050)ⁿ / k(0.3)ᵃ(0.050)ᵇ(0.050)ⁿ

1 = 2ᵇ

b = 0

If we now take the expressions from trial 3 and 1 and divide them, we can obtain "n":

rate 3/rate 1 = k(0.3)ᵃ(0.050)⁰(0.01)ⁿ/ k(0.3)ᵃ(0.050)⁰(0.050)ⁿ

2.1 = 2ⁿ  Applying ln to both side of the equation:

ln 2.1 = n ln2

ln2.1/ln2 = n

1 ≅ n

Taking now the reaction in trial 5 and 1 and dividing them:

rate 5/rate 1 = k(0.4)ᵃ(0.050)⁰(0.050) / k(0.3)ᵃ(0.050)⁰(0.050)

4/3 = 4/3ᵃ  

a = 1

a)Then the rate law can be written as follows:

rate = k[Acetone][Br₂]⁰[H⁺]

It might be suprising that the rate of bromination of acetone does not depend on the concentration of Br₂. However, looking at the reaction mechanism, you can find out why.

b) Now, we can find the constant k for every experiment and calculate its average value:

rate / [Acetone][Br₂]⁰[H⁺]  = k

For reaction 1:

k1 = 5.7 ×10⁻⁵M/s / (0.3 M)(0.050 M) = 3.8 ×10⁻³ M⁻¹ · s⁻¹

Reaction 2: k2 = 5.7 ×10⁻⁵M/s / (0.30 M)(0.050 M) = 3.8 ×10⁻³ M⁻¹ · s⁻¹

Reaction 3: k3 = 1.2 ×10⁻⁴M/s / (0.30 M)(0.10 M) = 4.0 ×10⁻³ M⁻¹ · s⁻¹

Reaction 4: k4 = 3.1 ×10⁻⁴M/s / (0.40 M)(0.20 M) = 3.9 ×10⁻³ M⁻¹ · s⁻¹

Reaction 5: k5 = 7.6 ×10⁻⁵M/s / (0.4 M)(0.05 M) = 3.8 ×10⁻³ M⁻¹ · s⁻¹

Averge value of k:

k = (k1 + k2 + k3 + k4 + k5)/5 = 3.86 × 10⁻³ M⁻¹ · s⁻¹

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number of H₂SO₄ mol reacting - 2 mol
according to molar ratio of 1:1
number of Ca(OH)₂ mol = number of H₂SO₄ moles 
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Net ionic equation for 2AgF(aq) + k2S = Ag2S (s) + 2KF(aq)
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Answer:

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