1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
kirza4 [7]
3 years ago
13

Two solutions, initially at 24.60 °C, are mixed in a coffee cup calorimeter (Ccal = 15.5 J/°C). When a 100.0 mL volume of 0.100

M AgNO3 solution is mixed with a 100.0 mL sample of 0.200 M NaCl solution, the temperature in the calorimeter rises to 25.30 °C. Determine the ∆H°rxn in kJ/mol AgCl for the reaction as written below. The density of the final solution is 1.00 g/mL and heat capacity of the final solution is 4.18 J/goC.
Chemistry
1 answer:
-Dominant- [34]3 years ago
5 0

Answer:

∆H°rxn in kJ/mol AgCl = - 59.61 kJ/mol

Explanation:

To solve this question we need to calculate the heat absorbed by the cup calorimeter and by the water in the solutions. We will also need to calculate the amount in moles produced by the reaction since we want to know the ∆H°rxn in kJ/mol AgCl .

mol AgNO₃ = 100 mL x 1L/1000 mL x 0.100 mol/L = 0.01 mol

mol NaCl = 100 mL x 1L/1000 mL x 0.200 mol/L = 0.02 mol

Therefore our limiting reagent is the 0.01 mol AgNO₃ and 0.01 mol AgCl will be produced according to the stoichiometry of the reaction:

AgNO₃ + NaCl ⇒ AgCl + NaNO₃

Heat absorbed by the water:

qw = m(H₂O) x c x ΔT where  m (H₂O) = 200 g ( the density of final solution is  1  g/ml)

c = specific heat of water = 4.18 J/gºC

ΔT = change in temperature =  (25.30 - 24.60 ) ºC = 0.7ºC

qw = 200 g x 4.18 J/gºC x 0.7 ºC = 585.20 J

Heat Absorbed by the calorimeter :

q cal = C cal x  ΔT  = 15.5 J/ºC x 0.7ºC = 10.85 J

Total Heat released by the combustion = qw + qcal = 585.20 J +10.85 J

=  596.05 J

We have to change the sign to this quantity since it is an exotermic reaction  ( ΔT is positive ) and have the ∆Hrxn

∆H rxn  = -596.05 J  

but this  is not what we are being asked since this heat was released by the formation of  0.0100 mol of AgCl so finally  

∆H°rxn = -596.05 J /0.01 mol  = -59,605 J/mol x 1 kJ/1000J = -59.61 kJ/mol

You might be interested in
I need the answer to 452 of arogon
yaroslaw [1]
I'm confused... is there more info? 
3 0
3 years ago
Which factor has the least effect on the rate of solution of a solid in a liquid?
vitfil [10]
The pressure will not affect the rate of solution.
4 0
3 years ago
Read 2 more answers
Assessment timer and count
ollegr [7]

Answer:

The answer to your question would be "the insect touching the trigger hairs".

Explanation:

I'm not much of an ex-plainer but I know this is the right answer because I took the test and got a 100%. Please trust me on this. If wrong, please tell me. This is what I was taught at school. Thank you and good day.

8 0
3 years ago
Read 2 more answers
What are the advantages and disadvantages of living in a group?
Feliz [49]
Advantages
people are there to help
never lonely
they could do things for you

disadvantages
loud
annoying to you
they don't do work
3 0
3 years ago
What is the electron configuration for sulfur? A. 1s2 2s2 2p6 3s2 3p4 B. 1s2 1p6 2s2 2p6 3s2 C. 1s2 2s2 2p6 3s2 3p3 4s1 D. 1s2 2
3241004551 [841]
Sulfur has two filled energy levels and six electrons on the third energy level. The corresponding electron configuration is A.
B is incorrect because there are no p orbitals at the first energy level, ie, no 1p orbitals. C is incorrect because the 4s1 electron would spontaneously drop into the 3p orbitals. D is incorrect because the 3d electrons would spontaneously drop into the 3p orbitals.
3 0
3 years ago
Read 2 more answers
Other questions:
  • H2S polar or nonpolar ?
    9·2 answers
  • Heat from our closet star the travels by radiation
    15·1 answer
  • What percentage of water on earth is fresh water
    14·2 answers
  • Please help :))
    12·1 answer
  • A 50 W engine generates 50 J of energy. How long did it run for?
    5·2 answers
  • Gaseous methane (CH_4) will react with gaseous oxygen (O_2) to produce gaseous carbon dioxide (CO_2) and gaseous water (H_2O). S
    7·1 answer
  • If you guys don’t mind can you explain to me why u think it’s either A, b, c, d plz and thank you
    13·1 answer
  • Can someone help balance this?
    6·1 answer
  • 1. write the complete chemical symbol for the ion with 14 protons 15 neutrons and 18 electrons
    8·1 answer
  • Number of electrons for all of these even the ones with a number by them ? Will give brainlist!!!!
    6·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!