Centre of Mass then axis of rotation and then moment of inertia. This was the toughest question for your level... happy to help ^_^. It was purely experimental question.
Answer:

Explanation:
The two cars are under an uniform linear motion. So, the distance traveled by them is given by:

is the same for both cars when the second one catches up with the first. If we take as reference point the initial position of the second car, we have:

We have
. Thus, solving for t:

Your answer is 632,100J which is Choice D
Answer:
B. 
Explanation:
Assuming we are dealing with a perfect gas, we should use the perfect gas equation:

With T the temperature, V the volume, P the pressure, R the perfect gas constant and n the number of mol, we are going to use the subscripts i for the initial state when the gas has 20 cubic inches of volume and absolute pressure of 5 psi, and final state when the gas reaches 10 psi, so we have two equations:
(1)
(2)
Assuming the temperature and the number of moles remain constant (number of moles remain constant if we don't have a leak of gas) we should equate equations (1) and (2) because
,
and R is an universal constant:
, solving for 


force=mass × acceleration
mass=force ÷ acceleration
acceleration=force ÷ mass