The concentrations of Pb+2(aq) and Cl-(aq) are expected to decrease (because you have initially very high values of [Pb2+] and [Cl-], they should decrease so that you equilibrium is reestablished, so that Qsp = Ksp).
Solids aren't measured using concentrations but the AMOUNT of PbCl2(s) is expected to increase.
It IS possible to have a system with Ksp > 1.8 x 10^-2 -- if you increase the temperature, then solubility and Ksp are both increased. It is also possible to have a system with Qsp > Ksp (as is true in this case). However, if Qsp > Ksp, the system will shift so that reequilibrium is reestablished. Over time, Qsp will be come equal to Ksp.
A solution is a homogeneous mixture of two or more substances. a solution doesn't allow light to scatter. the solute cannot be separated mechanically from the solution.
