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iren [92.7K]
3 years ago
12

An ideal gaseous reaction (which is a hypothetical gaseous reaction that conforms to the laws governing gas behavior) occurs at

a constant pressure of 50.0 atm and releases 73.2 kj of heat. before the reaction, the volume of the system was 7.60 l . after the reaction, the volume of the system was 2.00 l . calculate the total internal energy change, δe, in kilojoules. express your answer with the appropriate units.
Chemistry
1 answer:
pochemuha3 years ago
7 0

Total internal energy change is equals to -44.83kJ

Q=-73.2kJ (negative sign indicates that heat was released by the system),

P= 50.0atm

ΔU= Q + W, FIRST LAW OF THERMODYNAMICS..........(1)

ΔV= Final volume - initial volume= 2.00 litre - 7.60litre= -5.60litre

work done by the system (w)= -PΔV

w= -(50.0×(-5.60)) atm×litre=  280atm litre

1 atm litre= 101.325J

w= 280 ×101.325 J= 28,371J

1kJ=1000J,

w=28.37KJ,

so putting in the values in equation (1)...

energy change(ΔU) = -73.2 kJ + 28.37 kJ

= - 44.83 kJ

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5 0
3 years ago
Which gas will effuse at the rate closest At a particular pressure and temperature, nitrogen gas effuses at the rate of 79mLs. U
Contact [7]

Answer : The rate of effusion of sulfur dioxide gas is 52 mL/s.

Solution :

According to the Graham's law, the rate of effusion of gas is inversely proportional to the square root of the molar mass of gas.

R\propto \sqrt{\frac{1}{M}}

or,

(\frac{R_1}{R_2})=\sqrt{\frac{M_2}{M_1}}       ..........(1)

where,

R_1 = rate of effusion of nitrogen gas = 79mL/s

R_2 = rate of effusion of sulfur dioxide gas = ?

M_1 = molar mass of nitrogen gas  = 28 g/mole

M_2 = molar mass of sulfur dioxide gas = 64 g/mole

Now put all the given values in the above formula 1, we get:

(\frac{79mL/s}{R_2})=\sqrt{\frac{64g/mole}{28g/mole}}

R_2=52mL/s

Therefore, the rate of effusion of sulfur dioxide gas is 52 mL/s.

4 0
3 years ago
If 21.00 mL of a 0.68 M solution of C6H5NH2 required 6.60 mL of the strong acid to completely neutralize the solution, what was
Andru [333]

Answer:

pH = 2.46

Explanation:

Hello there!

In this case, since this neutralization reaction may be assumed to occur in a 1:1 mole ratio between the base and the strong acid, it is possible to write the following moles and volume-concentrations relationship for the equivalence point:

n_{acid}=n_{base}=n_{salt}

Whereas the moles of the salt are computed as shown below:

n_{salt}=0.021L*0.68mol/L=0.01428mol

So we can divide those moles by the total volume (0.021L+0.0066L=0.0276L) to obtain the concentration of the final salt:

[salt]=0.01428mol/0.0276L=0.517M

Now, we need to keep in mind that this is an acidic salt since the base is weak and the acid strong, so the determinant ionization is:

C_6H_5NH_3^++H_2O\rightleftharpoons  C_6H_5NH_2+H_3O^+

Whose equilibrium expression is:

Ka=\frac{[C_6H_5NH_2][H_3O^+]}{C_6H_5NH_3^+}

Now, since the Kb of C6H5NH2 is 4.3 x 10^-10, its Ka is 2.326x10^-5 (Kw/Kb), we can also write:

2.326x10^{-5}=\frac{x^2}{0.517M}

Whereas x is:

x=\sqrt{0.517*2.326x10^{-5}}\\\\x=3.47x10^-3

Which also equals the concentration of hydrogen ions; therefore, the pH at the equivalence point is:

pH=-log(3.47x10^{-3})\\\\pH=2.46

Regards!

6 0
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Are mass vs. density the same
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Mass is the amount of matter in an object. Density is the degree of compactness of a substance
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What form (what compound) is the carbon in?
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Compounds that primarily contain carbon are known as organic compounds.
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