CH4 has more ideal gas behavior than CCl4 due to its higher intermolecular interaction.
We must note that ideal gases have minimal interaction with each other. Hence, in deciding which gas has ideal gas behavior, we have to consider the gas that has the least degree of intermolecular interaction.
However, the both gases contain nonpolar molecules but CCl4 has a greater molecular mass and has more intermolecular interaction than CH4 hence CH4 has greater ideal gas behavior than CCl4.
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The overall rate law in terms of the initial rate of the reaction is:
= ![k_{overall} [H_{2} SO_{4} ]^{2} [C_{6}H_{6}]](https://tex.z-dn.net/?f=k_%7Boverall%7D%20%5BH_%7B2%7D%20SO_%7B4%7D%20%5D%5E%7B2%7D%20%5BC_%7B6%7DH_%7B6%7D%5D)
The Sulfonation of benzene has the following mechanism:
(1) 
⇌ 
[fast]
(2) 
→ 
[slow]
(3) 
→ 
[fast]
(4) 
→ 
[fast]
<h3>Calculation of rate law:</h3>
Given that the reaction's slowest step is the rate-dependent step, the following is the definition of rate law:
Rate = ![k_{2} [SO_{3} ][C_{6} H_{6} ]](https://tex.z-dn.net/?f=k_%7B2%7D%20%5BSO_%7B3%7D%20%5D%5BC_%7B6%7D%20H_%7B6%7D%20%5D)
However, the issue is that because 
is an intermediate, it cannot be accounted for in the general rate legislation.
The following rate rule governs the synthesis of :
Rate = ![k_{1}[H_{2} SO_{4} ]^{2}](https://tex.z-dn.net/?f=k_%7B1%7D%5BH_%7B2%7D%20SO_%7B4%7D%20%20%5D%5E%7B2%7D)
Consequently, if we replace equation 1 with equation 2,
Rate is determined to be =
Hence, the overall rate law in terms of the initial rate of the reaction is:
=
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use a mortar & pestle to grind the solute into smaller particles, thus increasing the surface area.
Answer:
The answer is
<h2>241.15 kPa</h2>
Explanation:
To find the pressure in kilopascals we must first find the pressure in Pascal
To find the pressure in Pascal we use the conversion
1 atm = 101 , 325 Pa
If 1 atm = 101325 Pa
then 2.38 atm = 2.38 × 101325
= 241153.5 Pa
Converting it into kPa we have the final answer as
<h3>241.15 kPa</h3>
Hope this helps you
