The one with the highest pH would be a solution with 100 mL of water and also 20 mL of 0.1 M NaOH is added. Solutions without buffers would have the highest pH since the resistance to change is very low. Hope this answers the question.
Quantitative data are measures of values or counts and are expressed as numbers. The best tool out of all shown to deal with a large amount of numerical data is a computer