<u>Answer:</u> The temperature when the volume and pressure has changed is -27.26°C
<u>Explanation:</u>
To calculate the temperature when pressure and volume has changed, we use the equation given by combined gas law. The equation follows:

where,
are the initial pressure, volume and temperature of the gas
are the final pressure, volume and temperature of the gas
We are given:
![P_1=725mmHg\\V_1=12L\\T_1=30.00^oC=[30+273]K=303K\\P_2=252mmHg\\V_2=28L\\T_2=?K](https://tex.z-dn.net/?f=P_1%3D725mmHg%5C%5CV_1%3D12L%5C%5CT_1%3D30.00%5EoC%3D%5B30%2B273%5DK%3D303K%5C%5CP_2%3D252mmHg%5C%5CV_2%3D28L%5C%5CT_2%3D%3FK)
Putting values in above equation, we get:

Converting this into degree Celsius, we get:


Hence, the temperature when the volume and pressure has changed is -27.26°C
Answer:
4.8 g/mL is the density of chloroform vapor at 1.00 atm and 298 K.
Explanation:
By ideal gas equation:

Number of moles (n)
can be written as: 
where, m = given mass
M = molar mass

where,
which is known as density of the gas
The relation becomes:
.....(1)
We are given:
M = molar mass of chloroform= 119.5 g/mol
R = Gas constant = 
T = temperature of the gas = 
P = pressure of the gas = 1.00 atm
Putting values in equation 1, we get:

4.8 g/mL is the density of chloroform vapor at 1.00 atm and 298 K.
No units are provided in the data table, though one would usually assume that 0.244 is molarity of NaOH, and buret data of 14.7 is probably the final volume of NaOH in mL. No identification is given for the 38, but maybe this is the initial buret volume in mL.
If the buret was rinsed with water, it should have been left to dry for some time, or else the added water may slightly dilute the NaOH solution placed in it.