Answer:
When the concentration of F- exceeds 0.0109 M, BaF2 will precipitate.
Explanation:
Ba²⁺(aq) + 2 F⁻(aq) <----> BaF₂(s)
When BaF₂ precipitates, the Ksp relation is given by
Ksp = [Ba²⁺] [F⁻]²
[Ba²⁺] = 0.0144 M
[F⁻] = ?
Ksp = (1.7 × 10⁻⁶)
1.7 × 10⁻⁶ = (0.0144) [F⁻]²
[F⁻]² = (1.7 × 10⁻⁶)/0.0144 = 0.0001180555
[F⁻] = √0.0001180555 = 0.01086 M = 0.0109 M
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100.0ml*0.400m =xml *2.00m
x=100.0*0.400/2.00= 20 ml 2.0 m CaCl2
you need to take 20 ml 2.0 m CaCl2 and dilute it with water up to 100.0 ml
A is the answer to this question. Thank you.