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Wewaii [24]
4 years ago
14

S-2-iodooctane lost his opticaly activity in soln on tratment wwithNaI. Explain

Chemistry
1 answer:
IceJOKER [234]4 years ago
5 0

Answer:

Repeated SN2 reactions occur leading to the formation of a racemic mixture

Explanation:

S-2-iodooctane is a chiral alkyl halide with an asymmetric carbon atom. The presence of an asymmetric carbon atom implies that it can rotate plane polarized light and thus lead to optical isomerism. The two configurations of the compound are R/S according to the Cahn-Prelong-Ingold system.

However, when S-2-iodooctane is treated with sodium iodide in acetone, repeated SN2 reactions occur since the iodide ion is both a good nucleophile and a good leaving group. Hence a racemic modification is formed in the system with time hence we end up with (±)- Iodooctane.

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3 years ago
If Matteo has a model car with a volume of 100 mL and a mass of 200 g, what is the density of their model car?
OLEGan [10]

Answer:

<h2>2 g/mL</h2>

Explanation:

The density of a substance can be found by using the formula

density =  \frac{mass}{volume}  \\

From the question we have

density =  \frac{200}{100}  \\

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<h3>2 g/mL</h3>

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The decayed organic material that gives soil its dark brown or black color is called
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Predict the mass of iron (III) sulfide produced when 3.0 g of iron filings react completely with 2.5 g of yellow sulfur solid, S
gladu [14]

The complete balanced chemical reaction to this would be:

<span>2 Fe  +  3/8 S8  -->  Fe2S3</span>

 

First convert mass into number of moles.

moles Fe = 3 g / (55.845 g/mol) = 0.05372 mol Fe

moles S8 = 2.5 g / (256.52 g/mol) = 0.0097458 mol S8

 

Then we find the limiting reactant. The limiting reactant is the one which has lower (moles/coefficient) ratio.

Fe = 0.05372 / 2 = 0.02686

S8 = 0.0097458 / (3/8) = 0.02599

 

So since S8 has lower ratio, therefore it is the limiting reactant so we base our calculation from it. From the reaction, we get 1 mole of Fe2S3 for every 3/8 mol of S8, therefore:

moles Fe2S3 = 0.0097458 mol S8 * (1 mole Fe2S3 / 3/8 mol S8)

moles Fe2S3 = 0.02599 mol

 

The molar mass of Fe2S3 is 207.9 g/mol, so the mass is:

mass Fe2S3 = 0.02599 mol * 207.9 g/mol

<span>mass Fe2S3 = 5.4 grams</span>

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