He could be blindfolded and know which was his and which was his sister's. All he would need to do is pick them both up and if they were too big then pick them up one at a time. The lumber might make it harder to tell, but this is a question about physical properties.
So there is a change in mass which for the purpose of this question should be quite different. His sister's ought to be much lighter than his. He would find it easier to pick up.
When electrons are added to the outermost shell of a carbon atom, it forms an anion.
If the concentration of acetyl chloride is increased ten times the rate of reaction is increased ten times.
The conversion of acetyl chloride to methyl acetate is a substitution reaction. Recall that a substitution reaction is one in which a moiety in a molecule is replaced by another.
In this reaction, the CH3O- ion replaces the chloride ion. In the first step, the CH3O- ion attacks the substrate in a slow step. This creates a tetrahedral intermediate. Loss of the chloride ion yields the methyl acetate product.
The rate determining step is the formation of the tetrahedral intermediate. Since the reaction is first order in the acetyl chloride, if its concentration is increased ten times the rate of reaction is increased ten times.
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