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forsale [732]
3 years ago
6

The reaction of pyrrole with bromine forms predominantly __________. View Available Hint(s) The reaction of pyrrole with bromine

forms predominantly __________. 2-bromopyrrole 2,3-dibromopyrrole N-bromopyrrole 3-bromopyrrole

Chemistry
1 answer:
xenn [34]3 years ago
5 0

Answer:

a) 2-bromopyrrole

Explanation:

Our options for this questions are:

a) 2-bromopyrrole

b) 2,3-dibromopyrrole

c) N-bromopyrrole

d) 3-bromopyrrole

To understand how the reaction works we have to start with the <u>resonance structures</u>. (Figure 1), on these structures, we will obtain a n<u>egative charge on carbon 2</u> in the pyrrole ring, therefore on this carbon we can generate an attack to an electrophile.

The second step is to check how the mechanism take place. An <u>electrophile is generated</u> by the Br_2 and FeBr_3. This electrophile can be <u>attacked</u> by the negative charge on carbon 2 producing the 2-bromopyrrole. (See figure 2).

I hope it helps!

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Answer: (Structure attached).

Explanation:

This type of reaction is an aromatic electrophilic substitution. The overall reaction is the replacement of a proton (H +) with an electrophile (E +) in the aromatic ring.

The aromatic ring in p-fluoroanisole has two sustituents, an <u>halogen</u> and a <u>methoxy group</u>, which are <em>ortho-para</em> directing substituents.

Aryl sulfonic acids are easily synthesized by an electrophilic substitution reaction aromatic using <u>sulfur trioxide as an electrophile</u> (very reactive).

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  3. The sulfonate group can be protonated in the presence of a strong acid (H₂SO₄).

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Using the equations 2 Sr(s) + O₂ (g) → 2 SrO (s) ∆H° = -1184 kJ/mol SrO (s) + CO₂ (g) → SrCO₃ (s) ∆H° = -234 kJ/mol CO₂ (g) → C(
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<u>Answer:</u> The \Delta H^o_{rxn} for the reaction is 72 kJ.

<u>Explanation:</u>

Hess’s law of constant heat summation states that the amount of heat absorbed or evolved in a given chemical equation remains the same whether the process occurs in one step or several steps.

According to this law, the chemical equation is treated as ordinary algebraic expressions and can be added or subtracted to yield the required equation. This means that the enthalpy change of the overall reaction is equal to the sum of the enthalpy changes of the intermediate reactions.

The given chemical reaction follows:

2SrCO_3(s)\rightarrow 2Sr(s)+2C(s)+3O_2(g)      \Delta H^o_{rxn}=?

The intermediate balanced chemical reaction are:

(1) 2Sr(s)+O_2(g)\rightarrow 2SrO(s)    \Delta H_1=-1184kJ

(2) SrO(s)+CO_2(g)\rightarrow SrCO_3(s)     \Delta H_2=-234kJ      ( × 2)

(3) CO_2(g)\rightarrow C(s)+O_2(g)     \Delta H_3=394kJ    ( × 2)

The expression for enthalpy of the reaction follows:

\Delta H^o_{rxn}=[1\times (\Delta H_1)]+[2\times (-\Delta H_2)]+[2\times (\Delta H_3)]

Putting values in above equation, we get:

\Delta H^o_{rxn}=[(1\times (-1184))+(2\times -(-234))+(2\times (394))]=72kJ

Hence, the \Delta H^o_{rxn} for the reaction is 72 kJ.

4 0
3 years ago
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