Water is not alive because it has no living organisms.
Pure substances are substances which are homogenous in nature. They either consists of atoms of 1 kind or molecules of 1 kind. Atoms are seen in elements, where as molecules are seen in compounds like Acids, Bases, etc.
They mostly have fixed properties like boiling and melting points and are uniform in nature. :D
2KClO₃ → 2KCl + 3O₂
mole ratio of KClO₃ to O₂ is 2 : 3
∴ if moles of O₂ = 5 mol
then moles of KClO₃ =

= 3.33 mol
Mass of KClO₃ needed = mol of KClO₃ × molar mass of KClO₃
= 3.33 mol × ((39 × 1) + (35.5 × 1) + (16 × 3) g/mol
= 407.93 g