The given question is incomplete. the complete question is:
The world burns the fossil fuel equivalent of approximately
kg of petroleum per year. Assume that all of this petroleum is in the form of octane. Calculate how much CO2 in kilograms is produced by world fossil fuel combustion per year.( Hint: Begin by writing a balanced equation for the combustion of octane.)
Answer: 
Explanation:
Combustion is a chemical reaction in which hydrocarbons are burnt in the presence of oxygen to give carbon dioxide and water.
According to the law of conservation of mass, mass can neither be created nor be destroyed. Thus the mass of products has to be equal to the mass of reactants. The number of atoms of each element has to be same on reactant and product side. Thus chemical equations are balanced.

To calculate the moles :

According to stoichiometry :
As 2 moles of octane give = 16 moles of 
Thus
of octane give =
of 
Mass of 
Thus
of
is produced by world fossil fuel combustion per year.
Double replacement.
Ba(OH)2 + H2SO4 ====> 2H2O + BaSO4
The moles of potassium dichromate , K₂Cr₂O₇ are required to prepare a 250 mL solution of with a concentration of 2.16 M is 0.54 mol.
given that :
molarity = 2.16 M
volume = 250 mL = 0.25 L
the molarity is given as :
molarity = number of moles / volumes in L
from this we can calculate the number of moles, we get :
number of moles of K₂Cr₂O₇ = molarity × volume
number of moles of K₂Cr₂O₇ = 2.16 × 0.25
number of moles of K₂Cr₂O₇ = 0.54 mol
Thus, The moles of potassium dichromate , K₂Cr₂O₇ are required to prepare a 250 mL solution of with a concentration of 2.16 M is 0.54 mol.
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There is only one product in a synthesis reaction.