The quantity of NaOH required to reach the third equivalence point is 20mL.
Using the titration formula,
CaVa/CbVb = Na/Nb
Where,
Ca = concentration of citric acid (0.200 M)
Cb = concentration of NaOH (0.750 M)
Va = Volume of citric acid (25.0 mL)
Vb = volume of NaOH (x mL)
Na = number of reacting mole of citric acid (3)
Nb = number of reacting mole of NaOH (1)
Therefore Vb ( x mL) =CaVaNb/CbNa
= 0.2× 25×3/0.75 ×1
= 15/0.75
Vb ( x mL) = 20 mL
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Answer:
= -356KJ
<em>therefore, the reaction where heat is released is exothermic reaction since theΔH is negative</em>
Explanation:
given that enthalpy of gaseous reactants decreases by 162KJ and workdone is -194KJ
then,
change in enthalpy (ΔH) = -162( released energy)
work(w) = -194KJ
change in enthalpy is said to be negative if the heat is evolved during the reaction while heat change(ΔH) is said to be positive if the heat required for the reaction occurs.
At constant pressure the change in enthalpy is given as
ΔH = ΔU + PΔV
ΔU = change in energy
ΔV = change in volume
P = pressure
w = -pΔV
therefore,
ΔH = ΔU -W
to evaluate energy change we have,
ΔU =ΔH + W
ΔU = -162+ (-194KJ)
= -356KJ
<em>therefore, the reaction where heat is released is exothermic reaction since theΔH is negative</em>
Answer:
Farthest from the carbonyl carbon.
Explanation:
Reference carbon that determined the absolute D and L configuration is located farthest from the carbonyl carbon.
In other words, reference carbon is that assymentric carbon which is located farthest from the carbolyl carbon and has configuration similar to D- or L-glyceraldehyde isomers.
D and L configuration is decided by the direction of -OH group attached to the reference carbon.
In L-isomer, -OH group is attached to the left side of the reference carbon and in D-isomer, -OH group is attached to the right side of the reference carbon.
