Blank 1: nothing (to keep 2 total nitrogen)
blank 2: 3 (to make 6 total hydrogen)
blank 3: 2 (to make 2 total nitrogen and 6 total hydrogen)
hope this helps!! :)
Answer: 10.9 mol.
Explanation:
- To understand how to solve this problem, we must mention the reaction equation where water produced from PbO₂.
Pb + PbO₂ + 2H₂SO₄ → 2PbSO₄ + 2H₂O
- Now, it is a stichiometric oriented problem, that 1 mole of PbO₂ produces 2 moles of H₂O.
Using cross multiplication:
1.0 mole of PbO₂ → 2.0 moles of H₂O
5.43 moles of PbO₂ → ??? moles of water
The moles of water produced = (5.43 x 2.0) = 10.86 moles ≅ 10.9 moles.
Alkenes on reacting with ozone results in the formation of ozonide which undergo reductive cleavage in presence of dimethyl sulfide to form carbonyl compounds (aldehyde or ketone). Whereas in presence of hydrogen peroxide it undergoes oxidative cleavage to form carboxylic acids or ketones.
Since, A alkene yields 4-heptanone only on treatment with ozone and DMS thus, it implies that both the chains on the side of the double-bond are similar the product is 4-heptanone that means the double bond is present between the chains at the 4th carbon. Therefore the structure of compound A is 4,5-dipropyloct-4-ene.
The reaction is as shown in the image.
The reaction of A with m-CPBA (meta-perchlorobenzoic acid) followed by aqueous acid
is shown in the image.
m-CPBA (meta-perchlorobenzoic acid) is a peracid and forms epoxides on reacting with alkenes.
Water boils when its vapor pressure equals the prevailing atmospheric pressure over the water. In order for water to boil at 50 ºC, the pressure over the water would need to be reduced to a point greater equal to the vapor pressure of the water (92.5 torr).