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tatiyna
2 years ago
10

A compound with molecular formula C6H15N exhibits a singlet at d 0.9 ppm (1H), a triplet at 1.10 ppm (3H), a singlet at 1.15 ppm

(9H), and a quartet at 2.6 ppm (2H) in its 1HNMR spectrum. Its IR spectrum shows one medium absorption band near 3400 cm-1. What is the structure of this compound?

Chemistry
1 answer:
Triss [41]2 years ago
5 0

Answer:

CH3 - CH2 - NH - C(CH3)3

Explanation:

The 1HNMR is the acronym for Proton nuclear magnetic resonance and it is used in chemistry or Chemical laboratory for the analysis and identification of compounds.

In order to be able to answer the question accurately you have to have the tables containing all the values for chemical shift. The Chemical shift is measured in ppm and it occur due to Resonance frequency variation.

From the table, a singlet at 1.15 ppm (9H) is - C(CH3)3.

A singlet at d 0.9 ppm (1H) shows the presence of a secondary amine group, that is -R2NH group.

A triplet at 1.10 ppm (3H) shows that we have;

CH3- CH2-

A quartet at 2.6 ppm (2H) shows that we have;

-CH2 - CH3.

Therefore, joining all together we have;

CH3 - CH2 - NH - C(CH3)3.

Kindly check attached file for the picture of the structure.

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mario62 [17]

Answer:

The order will be:

CCH > CHCH₂ > CH₂CH₃> CH₃

Explanation:

According to Cahn-Ingold-Prelog system we rank the groups based on the atomic number of directly attached atom with the chiral carbon.

For example: between C and H, we rank Carbon first.

If the same atoms are attached for different groups then we prioritized based on the second element with highest atomic number.

For example:

Among CH₃ and C₂H₅, the priority will be given to C₂H₅.

If an atom is double or triple bonded to the directly attached atom then each pi bond is considered to be a new atom.

Hence CH=CH₂ means, that there are two carbons attached to CH carbon.

So the order based on above selection rules will be:

CCH > CHCH₂ > CH₂CH₃> CH₃

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Now first look at EC of Fluorine(F)

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Look at the EC

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