The relation between vapour pressure , enthalpy of vapourisation and temperature is
ln (88/ 39) = DeltaH / 8.314 (1 / 318 - 1 / 298)
0.814 = DeltaH / 8.314 (2.11 X 10^-4 )
DeltaH = -32.07 kJ
What are 3 things an Apple, Knife and Mirror have in common?
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We need to know the value of van't hoff factor.
The van't hoff factor is: 2.66 or 2.7 (approximately)
(NH₄)₂SO₄ is an ionic compound, so it dissociates in solution and produces 3 ionic species. Therefore van't hoff factor is more than one.
From the equation: Δ=i
.m, where Δ
= elevation of boiling point=102.5 - 100=2.5°C.
m=molality of solute=1.83 m (Given)
= Ebullioscopic constant or Boiling point elevation constant= 0.512°C/m (Given)
i= Van't Hoff factor
So, 2.5= i X 0.512 X 1.83
i=
i=2.66= 2.7 (approx.)