Answer:
Less
Explanation:
Since [Cu(NH3)4]2+ and [Cu(H2O)6]2+ are Octahedral Complexes the transitions between d-levels explain the majority of the absorbances seen in those chemical compounds. The difference in energy between d-levels is known as ΔOh (ligand-field splitting parameter) and it depends on several factors:
- The nature of the ligand: A spectrochemical series is a list of ligands ordered on ligand strength. With a higher strength the ΔOh will be higher and thus it requires a higher energy light to make the transition.
- The oxidation state of the metal: Higher oxidation states will strength the ΔOh because of the higher electrostatic attraction between the metal and the ligand
A partial spectrochemical series listing of ligands from small Δ to large Δ:
I− < Br− < S2− < Cl− < N3− < F−< NCO− < OH− < C2O42− < H2O < CH3CN < NH3 < NO2− < PPh3 < CN− < CO
Then NH3 makes the ΔOh higher and it requires a higher energy light to make the transition, which means a shorter wavelength.
6.52 × 10⁴ L. (3 sig. fig.)
<h3>Explanation</h3>
Helium is a noble gas. The interaction between two helium molecules is rather weak, which makes the gas rather "ideal."
Consider the ideal gas law:
,
where
- is the pressure of the gas,
- is the volume of the gas,
- is the number of gas particles in the gas,
- is the ideal gas constant, and
- is the absolute temperature of the gas in degrees Kelvins.
The question is asking for the final volume of the gas. Rearrange the ideal gas equation for volume:
.
Both the temperature of the gas, , and the pressure on the gas changed in this process. To find the new volume of the gas, change one variable at a time.
Start with the absolute temperature of the gas:
- ,
- .
The volume of the gas is proportional to its temperature if both and stay constant.
- won't change unless the balloon leaks, and
- consider to be constant, for calculations that include .
.
Now, keep the temperature at and change the pressure on the gas:
- ,
- .
The volume of the gas is proportional to the reciprocal of its absolute temperature if both and stays constant. In other words,
(3 sig. fig. as in the question.).
See if you get the same result if you hold constant, change , and then move on to change .
Answer:
<h3>it is important to carefully examine chemical reactions because there are many ways substances can be <em><u>reacting</u></em> without a chemical reaction taking place.</h3>