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wel
2 years ago
14

An analytical chemist weighs out of an unknown monoprotic acid into a volumetric flask and dilutes to the mark with distilled wa

ter. She then titrates this solution with solution. When the titration reaches the equivalence point, the chemist finds she has added of solution. Calculate the molar mass of the unknown acid. Be sure your answer has the correct number of significant digits.
Chemistry
1 answer:
Tatiana [17]2 years ago
4 0

The given question is incomplete. The complete question is as follows.

An analytical chemist weighs out 0.093 g of an unknown monoprotic acid into a 250 mL volumetric flask and dilutes to the mark with distilled water. He then titrates this solution with 0.1600 M NaOH solution. When the titration reaches the equivalence point, the chemist finds he has added 6.5 mL of NaOH solution. Calculate the molar mass of the unknown acid. Round your answer to 2 significant digits.

Explanation:

The given data is as follows.

   Mass of monoprotic acid = 0.093 g,

   Volume of monoprotic acid = 250 mL,

  [NaOH] = 0.1600 M, and volume of NaOH required at reaches the equivalence point = 6.5 mL.

Now, first of all we will calculate the moles of NaOH as follows.

        Moles of NaOH = molarity × volume (L)

                             = 0.1600 M × 0.0065 L

                             = 0.00104 moles

Let us assume that monoprotic acid is HA. And, it is known that monoprotic acid has 1 hydrogen ion and NaOH is also monoprotic base, means it has 1 hydroxide ion. Therefore, the reaction will be as follows.

       HA + NaOH \rightarrow NaA + H_{2}O

Hence, 1 mole of NaOH = 1 mole of HA

So, 0.00104 moles of NaOH = 0.00104 moles of HA

Now, we will calculate the molar mass of unknown acid as follows.

      Molar mass of unknown acid = \frac{mass}{moles}

                                  = \frac{0.093 g}{0.00104 moles}

                                  = 89.42 g/mol

Thus, we can conclude that molar mass of the unknown acid is 89.42 g/mol.

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Explanation:

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Pb(NO_3)_2(aq) + Na_2SO_4(aq)\rightarrow PbSO_4(s)+2NaNO_3(aq)

Pb(NO_3)_2(aq)\rightarrow Pb^{2+}(aq)+2NO_3^{-}(aq)

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Pb^{2+}(aq)+2NO_3^{-}(aq)+2Na^++SO_4^{2-}(aq)\rightarrow PbSO_4(s)+2Na^++2NO_3^{-}(aq)

Removing common ions from both sides, we get the net ionic equation:

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NiCl_2(aq) + NH4NO_3(aq) \rightarrow Ni(NO_3)_2+NH_4Cl(aq)

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c. Fe_Cl2(aq) + Na_2S(aq) →

FeCl_2(aq) + Na_2S(aq)\rightarrow FeS(s)+2NaCl(aq)

FeCl_2(aq)\rightarrow Fe^{2+}(aq)+2Cl^{-}(aq)

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3 years ago
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Answer:

a) \triangle G^{0} = 7.31 kJ/mol

b) K_{-1} = 0.0594 m^{-1} s^{-1}

Explanation:

Equation of reaction:

                                     2 XO_{2} (g) + O_{2} (g) \rightleftharpoons 2XO_{3} (g)

Initial pressure                  3              1              0

Pressure change             2P           1P             2P

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Pressure of XO2 = 3 - 2P = 3 - 2(0.25)

Pressure of XO2 =2.5 atm

Pressure of O2 = 1 - P = 1 -0.25

Pressure of O2 = 0.75 atm

Pressure of XO3 = 2P = 2 * 0.25

Pressure of XO3 = 0.5 atm

From the reaction, equilibrium constant can be calculated using the formula:

K_{p} = \frac{[PXO_{3}] ^{2} }{[PXO_{2}] ^{2}[PO_{2}] }

K_{p} = \frac{0.5^2}{2.5^2 *0.75} \\K_{p} = 0.0533 = K_{eq}

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K_{1} = 7.8 * 10^{-2} m^{-2} s^{-1}

K_{c} = K_{p}RT\\K_{c} = 0.0533* 0.0821 * 300\\K_{c} = 1.313 m^{-1}

K_{-1} = \frac{K_{1} }{K_{c} } \\K_{-1} = \frac{7.8 * 10^{-2}  }{1.313 }\\K_{-1} = 0.0594 m^{-1} s^{-1}

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