Answer: The reaction order with respect to A is m
Explanation:
Order of the reaction is defined as the sum of the concentration of terms on which the rate of the reaction actually depends. It is the sum of the exponents of the molar concentration in the rate law expression.
Elementary reactions are defined as the reactions for which the order of the reaction is same as its molecularity and order with respect to each reactant is equal to its stoichiometric coefficient as represented in the balanced chemical reaction.
For the given reaction:
![Rate=k[A]^m[B]^n](https://tex.z-dn.net/?f=Rate%3Dk%5BA%5D%5Em%5BB%5D%5En)
In this equation, the order with respect to each reactant is not equal to its stoichiometric coefficient which is represented in the balanced chemical reaction.
Hence, this is not considered as an elementary reaction.
Order with respect to A = m
Order with respect to B = n
Overall order = m+n
Thus order with respect to A is m.
This
can be solved using Dalton's Law of Partial pressures. This law states that the
total pressure exerted by a gas mixture is equal to the sum of the partial
pressure of each gas in the mixture as if it exist alone in a container. In
order to solve, we need the partial pressures of the gases given. Calculations
are as follows:<span>
<span>P = 3.00 atm + 1.80 atm + 0.29 atm + 0.18 atm + 0.10 atm</span></span>
<span><span>P = 5.37 atm</span></span>
C unbalanced force is occuring
First find the number of moles of sulfur using dimensional analysis with avogadro’s number as the conversion factor. 4.2*10^24 atoms * (1 mol/6.022*10^23 atoms) = 7.0 mol sulfur. The molar mass of sulfur is 32.06 g/mol, which is found on the periodic table as sulfur’s (S) atomic weight. Use dimensional analysis again with the molar mass of sulfur as the conversion factor. 7.0 mol * 32.06 g/mol = 224.42 g sulfur. Since the problems gives us two significant figures, round the mass of sulfur to 220 grams, or 2.2 * 10^2 g.
2) is the answer. graphite and diamonds possess the same molecular structes however the bonds and structures of diamonds are considerably stronger and more tightly packed respectively
