Question

If a system has a reaction quotient of 2.13 ✕ 10−15 at 100°C, what will happen to the concentrations of COBr2, CO, and Br2 as the reaction proceeds to equilibrium?

Answer 1

This is an incomplete question, here is a complete question.

Consider the following equilibrium at 100°C.

$COBr_2(g)\rightleftharpoons CO(g)+Br_2(g)$

$K_c=4.74\times 10^4$

Concentration at equilibrium:

$[COBr_2]=1.58\times 10^{-6}M$

$[Co]=2.78\times 10^{-3}M$

$[Br_2]=2.51\times 10^{-5}M$

If a system has a reaction quotient of 2.13 × 10⁻¹⁵ at 100°c, what will happen to the concentrations of COBr₂, Co and Br₂ as the reaction proceeds to equilibrium?

Answer : The concentrations of Co and Br₂ decreases and the concentrations of COBr₂ increases.

Explanation :

Reaction quotient (Q) : It is defined as the measurement of the relative amounts of products and reactants present during a reaction at a particular time.

The given balanced chemical reaction is,

$COBr_2(g)\rightleftharpoons CO(g)+Br_2(g)$

The expression for reaction quotient will be :

$Q=\frac{[CO][Br_2]}{[COBr_2]}$

In this expression, only gaseous or aqueous states are includes and pure liquid or solid states are omitted.

Now put all the given values in this expression, we get

$Q=\frac{(2.78\times 10^{-3})\times (2.51\times 10^{-5})}{(1.58\times 10^{-6})}=4.42\times 10^{-2}$

The given equilibrium constant value is, $K_c=4.74\times 10^4$

Equilibrium constant : It is defined as the equilibrium constant. It is defined as the ratio of concentration of products to the concentration of reactants.

There are 3 conditions:

When $Q>K_c$ that means product > reactant. So, the reaction is reactant favored.

When $Q$ that means reactant > product. So, the reaction is product favored.

When $Q=K_c$ that means product = reactant. So, the reaction is in equilibrium.

From the above we conclude that, the $Q$ that means product < reactant. So, the reaction is product favored that means reaction must shift to the product (right) to be in equilibrium.

Hence, the concentrations of Co and Br₂ decreases and the concentrations of COBr₂ increases.