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kari74 [83]
3 years ago
5

What is the molality of impurities in thesolvent? If the impurity is largely hexachloroethane, C2Cl6, how many grams of this imp

urity arethere per kg of CCl4?Once the mass of the impurity is determined, calculate the mass % purity:
Chemistry
1 answer:
Contact [7]3 years ago
5 0

Answer:

a) grams of this impurity per kg of CCl4 = 3.416 g/kg of solvent.

b) mass purity % = 99.66%

Explanation:

Given, the freezing point of pure CCl₄ = - 23°C

Presence of impurities lowers the freezing point to - 23.43°C

The freezing point depression constant, Kբ = 29.8°C/m

The lowered freezing point is related to all the parameters through the relation

ΔT = i Kբ × m

where ΔT is the lowered freezing point, that is, the difference between freezing point of pure substance (T⁰) and freezing point of substance with impurities (T).

i = Van't Hoff factor which measures how much the impurities influence/affect colligative properties (such as freezing point depression) and for most non-electrolytes like this one, it is = 1

Kբ = The freezing point depression constant = 29.8°C/m

m = Molality = ?

T⁰ - T = i Kբ m

- 23 - (-23.43) = 1 × 29.8 × m

m = 0.43/29.8 = 0.0144 mol/kg

Then, we're told to calculate impurity of the CCl₄

we convert the Molality to (gram of solute)/(kg of solvent) first

Solute = C₂Cl₆

Molar mass = 236.74 g/mol

So, (molality × molar mass) = (gram of solute)/(kg of solvent)

(gram of solute)/(kg of solvent) = 0.0144 × 236.74 = 3.416 (gram of solute)/(kg of solvent)

Mass purity % = (1000 g of pure substance)/(1000 g of pure substance + mass of impurity in 1000 g of pure substance)

1000 g of solvent contains 3.416 grams of impurities

Mass purity % =100% × 1000/(1003.416)

Mass purity % = 99.66 %

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vova2212 [387]

Answer:

a) 226.6 grams of Cl₂

b) 19.2 grams of C

c) 303.2 grams of TiCl₄ and 70.4 grams of CO₂

Explanation:

The balanced chemical reaction is the following:

TiO₂(s) + C(s) + 2 Cl₂(g) → TiCl₄(s) + CO₂(g)

(a) What mass of Cl₂ gas is needed to react with 1.60 mol TiO₂?

From the chemical equation, 1 mol of TiO₂ reacts with 2 moles of Cl₂. So, the stoichiometric ratio is 2 mol Cl₂/1 mol TiO₂. We multiply this ratio by the moles of TiO₂ we have to calculate the moles of Cl₂ we need:

1.60 mol TiO₂ x 2 mol Cl₂/1 mol TiO₂ = 3.2 mol Cl₂

Now, we convert from moles to mass by using the molecular weight (MW) of Cl₂:

MW(Cl₂) = 35.4 g/mol x 2 = 70.8 g/mol

mass of Cl₂= 3.2 mol x 70.8 g/mol = 226.6 g

<em>Therefore, 226.6 grams of Cl₂ are needed to react with 1.6 mol of TiO₂. </em>

(b) What mass of C is needed to react with 1.60 mol of TiO₂?

From the chemical equation, 1 mol of TiO₂ reacts with 1 moles of C(s). So, the stoichiometric ratio is 1 mol C/1 mol TiO₂. We multiply this ratio by the moles of TiO₂ we have to calculate the moles of C(s) we need:

1.60 mol TiO₂ x 1 mol C(s)/1 mol TiO₂ = 1.60 mol C(s)

So, we convert the moles of C(s) to grams as follows:

MW(C) = 12 g/mol

1.60 mol x 12 g/mol = 19.2 g C(s)

<em>Therefore, a mass of 19.2 grams of C is needed to react with 1.60 mol of TiO₂. </em>

(c) What is the mass of all the products formed by reaction with 1.60 mol of TiO₂?

From the chemical equation, we can notice that 1 mol of TiO₂ produces 1 mol of TiCl₄ and 1 mol of CO₂. So, from 1.60 moles of TiO₂, 1 mol of each product will be produced:

1 mol TiO₂/1 mol TiCl₄ ⇒ 1.60 mol TiO₂/1.60 mol TiCl₄

1 mol TiO₂/1 mol CO₂ ⇒ 1.60 mol TiO₂/1.60 mol CO₂

Finally, we convert the moles to grams by using the molecular weight of each compound:

MW(TiCl₄) = 47.9 g/mol Ti + (35.4 g/mol x 4 Cl) = 189.5 g/mol

1.60 mol x 189.5 g/mol = 303.2 g

MW(CO₂) = 12 g/mol C + (16 g/mol x 2 O) = 44 g/mol

1.60 mol x 44 g/mol = 70.4 g

<em>Therefore, from the reaction of 1.60 mol of TiO₂ are formed 303.2 grams of TiCl₄ and 70.4 grams of CO₂.</em>

3 0
3 years ago
Bradley was working in the lab. He accidentally poured a container of concentrated hydrochloric acid into his container of disti
nexus9112 [7]

Answer is: The solution has now become a good conductor of electricity.

Hydrochloric acid (HCl) dissociate on positive ions or cations of hydogen (H⁺) and negative ions or anions of chlorine (Cl⁻) accordinf to balanced chemical reaction:

HCl(aq) → H⁺(aq) + Cl⁻(aq).

When there are free cations and ions, water solution can conduct electricity.

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ehidna [41]

This question is incomplete because the options are missing; here are the options:

Which of the following is LESS dense than water?

The spoon

The glass

The tablets

The bubbles

The correct answer to this question is The bubbles

Explanation:

In general, the density of materials and substances affects their buoyancy. This implies in water less dense materials will float and those with higher density will sink. In the situation presented, the only element that is less dense than water are bubbles; this is shown by the movement of the bubbles as these originate in the bottom of the glass of water but they rise to the surface, which shows they are less dense than water.

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oksano4ka [1.4K]

Answer:

How the incident happened

Any chemicals involved in an incident

Any other hazards present in the lab

Explanation:

Above are the types of information that are necessary to communicate with emergency responders. The emergency responders ask the first question that how the incident happened. After that they ask that is there any harmful chemicals are present in the laboratory or what types of chemicals present in the laboratory. These questions were asked by the emergency responders in order to give the patient a suitable treatment.

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3 years ago
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Greeley [361]

Answer:

Both of the studies said that the mass of the atom is centered in the nucleus, which is positive, and there are electrons (negative particles) orbiting it. So, Rutheford and Nagaoka discovered that the atom can be divisible and it has an empty space.

But, in the model of Nagaoka, the nucleus was huge, and for Rutherford, the nucleus was really small, and the mass was concentrated. By his experiment with the gold sheets, the theory was appropriated. That's why Rutherford is credited with the discovery of the nucleus. Nagaoka was incorrect in his suppositions.

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3 years ago
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