Answer:fH = - 3,255.7 kJ/mol
Explanation:Because the bomb calorimeter is adiabatic (q =0), there'is no heat inside or outside it, so the heat flow from the combustion plus the heat flow of the system (bomb, water, and the contents) must be 0.
Qsystem + Qcombustion = 0
Qsystem = heat capacity*ΔT
10000*(25.000 - 20.826) + Qc = 0
Qcombustion = - 41,740 J = - 41.74 kJ
So, the enthaply of formation of benzene (fH) at 298.15 K (25.000 ºC) is the heat of the combustion, divided by the number of moles of it. The molar mass od benzene is: 6x12 g/mol of C + 6x1 g/mol of H = 78 g/mol, and:
n = mass/molar mass = 1/ 78
n = 0.01282 mol
fH = -41.74/0.01282
fH = - 3,255.7 kJ/mol
Answer:
The correct order of increasing reactivity toward nucleophilic acyl substitution is E < D < C < A < F < B.
Explanation:
The stability of the leaving group best determines the manner of reactivity of carboxylates to nucleophilic substitution after the substitution of the nucleophile to the leaving group. The leaving group should, therefore, be protonated with hydrogen ion in the solution to form a stable molecule. From the given list: The leaving group for A, Ethyl thioacetate will be ethanethiol. For B, Acetyl chloride will be Hydrochloric acid. For C, Sodium acetate will be Sodium Hydroxide. For D, Ethyl acetate will be Ethanol. For E, Acetamide will be Ammonia, and for F, Acetic anhydride will be Ethanoic acid. The reactivity of the substitution reaction is dependent on the stability of these leaving groups. The stability of these leaving groups depends on their pKa, and the more the pKa, the lesser the acidity of the leaving group, and the lower the reactivity. Therefore, considering their pKa: A is 8.5, B is -7, C is 13.8, D is 15.9, E is 36, and F is 4.8. When we rearrange this pKa in descending order, we have E, D. C, A, F, B. Which is also the increased reactivity of the nucleophilic acyl substitution.
From Melting! Hope this helped
N = M x V
n = 2.5 x 5.0
n = 12.5 moles of C6H12O6
