Explanation:
It is known that relation between heat energy and temperature change is as follows.
Q = 
where, q = heat energy
m = mass of the solution or solvent
= change in temperature
Hence, putting the given values into the above formula as follows.
Q = 
= 
= 34650 J
Now, calculate the energy of photons at wavelength 3.02 mm as follows.
E = 
where, h = planks constant = 
c = velocity of light =
m/s
= wavelength = 3.02 mm =
m (as 1 m = 1000 mm)
Therefore, putting the given values into the above formula as follows.
E = 
=
=
J
Now, the number of photons required of energy
J/photon for the total energy of 34650 J as follows.

n = 
= 
=
photons
or, =
photons
Thus, we can conclude that the minimum number of photons present are
.