1) Ca-37, with a half-life of 181.1(10) ms.
Answer:
8.279
Explanation:
The pH can be determined by hydrolysis of a conjugate base of weak acid at the equivalence point.
At the equivalence point, we have

= 25.00 x 0.200
= 5.00 m-mol
= 0.005 mol
Volume of the base that is added to reach the equivalence point is

Number of moles of 
= 0.005 mol
Volume at the equivalence point is 25 + 5 = 30.00 mL
Therefore, concentration of 
= 0.167 M
Now the ICE table :

I (M) 0.167 0 0
C (M) -x +x +x
E (M) 0.167-x x x
Now, the value of the base dissociation constant is ,



= 
Base ionization constant, ![$K_b = \frac{\left[HNO_2\right] \left[OH^- \right]}{\left[NO^-_2 \right]}$](https://tex.z-dn.net/?f=%24K_b%20%3D%20%5Cfrac%7B%5Cleft%5BHNO_2%5Cright%5D%20%5Cleft%5BOH%5E-%20%5Cright%5D%7D%7B%5Cleft%5BNO%5E-_2%20%5Cright%5D%7D%24)


So, ![$[OH^-]=1.9054 \times 10^{-6 } \ M$](https://tex.z-dn.net/?f=%24%5BOH%5E-%5D%3D1.9054%20%5Ctimes%2010%5E%7B-6%20%7D%20%5C%20M%24)
pOH =- ![$\log[OH^-]$](https://tex.z-dn.net/?f=%24%5Clog%5BOH%5E-%5D%24)
= 
=5.72
Now, since pH + pOH = 14
pH = 14.00 - 5.72
= 8.279
Therefore the ph is 8.279 at the end of the titration.
Answer:
a. Sn or Si ⇒ Sn
b. Br or Ga ⇒ Ga
c. Sn or Bi ⇒ similar in size
d. Se or Sn ⇒ Sn
Explanation:
The larger atom has a larger atomic radius. We have to consider how varies the atomic radius for chemical elements in the Periodic Table. In a group (column), the atomic radius increases from top to bottom while in a period (file), it increases from right to left.
a. Sn or Si ⇒ Sn
They are in the <u>same group</u>. Sn is on the top, so it has a larger atomic radius.
b. Br or Ga ⇒ Ga
They are in the <u>same period</u>. Ga is located at the left so it has a larger atomic radius.
c. Sn or Bi ⇒ similar
They are not in the same group neither the same period. Bi is located more at the bottom, so it would be larger than Sn, but Bi is also at the right side, so it would be smaller than Bi. Thus, they have comparable sizes.
d. Se or Sn⇒ Sn
They are not in the same group neither the same period. Se is located at the top and right side compared to Sn, so Sn is the larger atom.