The molar mass (atomic weight ) of sodium is 23.0 grams/mole and the molar mass of sodium azide, NaN3 , is the mass of sodium, 23.0 gram/mole added to the molar mass of three atoms of nitrogen (14.0 x 3 = 42 gram/mole) which equals 65.0 grams/mole. The percentage of sodium is 23.0 /65.0 x 100 % = 35 %
Potassium is placed where it is based on its properties and it's reactivity. It's also placed there based on it's atomic number.
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The answer is true that they have equal mases.