Answer:
a. 2 HgO(s) ⇒ 2 Hg(l) + O₂(g)
b. 0.957 g
Explanation:
Step 1: Write the balanced equation
2 HgO(s) ⇒ 2 Hg(l) + O₂(g)
Step 2: Convert 130.0 °C to Kelvin
We will use the following expression.
K = °C + 273.15
K = 130.0°C + 273.15
K = 403.2 K
Step 3: Calculate the moles of O₂
We will use the ideal gas equation.
P × V = n × R × T
n = P × V/R × T
n = 1 atm × 0.0730 L/0.0821 atm.L/mol.K × 403.2 K
n = 2.21 × 10⁻³ mol
Step 4: Calculate the moles of HgO that produced 2.21 × 10⁻³ moles of O₂
The molar ratio of HgO to O₂ is 2:1. The moles of HgO required are 2/1 × 2.21 × 10⁻³ mol = 4.42 × 10⁻³ mol.
Step 5: Calculate the mass corresponding to 4.42 × 10⁻³ moles of HgO
The molar mass of HgO is 216.59 g/mol.
4.42 × 10⁻³ mol × 216.59 g/mol = 0.957 g
Answer:
Mostly Para
Explanation:
First, let's assume that the molecule is the toluene (A benzene with a methyl group as radical).
Now the nitration reaction is a reaction in which the nitric acid in presence of sulfuric acid, react with the benzene molecule, to introduce the nitro group into the molecule. The nitro group is a relative strong deactiviting group and is metha director, so, further reactions that occur will be in the metha position.
Now, in this case, the methyl group is a weak activating group in the molecule of benzene, and is always ortho and para director for the simple fact that this molecule (The methyl group) is a donor of electrons instead of atracting group of electrons. Therefore for these two reasons, when the nitration occurs,it will go to the ortho or para position.
Now which position will prefer to go? it's true it can go either ortho or para, however, let's use the steric hindrance principle. Although the methyl group it's not a very voluminous and big molecule, it still exerts a little steric hindrance, and the nitro group would rather go to a position where no molecule is present so it can attach easily. It's like you have two doors that lead to the same place, but in one door you have a kid in the middle and the other door is free to go, you'll rather pass by the door which is free instead of the door with the kid in the middle even though you can pass for that door too. Same thing happens here. Therefore the correct option will be mostly para.
Answer:
The final temperature is 348.024°C.
Explanation:
Given data:
Specific heat of copper = 0.385 j/g.°C
Energy absorbed = 7.67 Kj (7.67×1000 = 7670 j)
Mass of copper = 62.0 g
Initial temperature T1 = 26.7°C
Final temperature T2 = ?
Solution:
Specific heat capacity:
It is the amount of heat required to raise the temperature of one gram of substance by one degree.
Formula:
Q = m.c. ΔT
Q = amount of heat absorbed or released
m = mass of given substance
c = specific heat capacity of substance
ΔT = change in temperature
ΔT = T2 - T1
Q = m.c. ΔT
7670 J = 62.0 g × 0.385 j/g °C ×( T2- 26.7 °C
)
7670 J = 23.87 j.°C ×( T2- 26.7 °C
)
7670 J / 23.87 j/°C = T2- 26.7 °C
T2- 26.7 °C = 321.324°C
T2 = 321.324°C + 26.7 °C
T2 = 348.024°C
The final temperature is 348.024°C.
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