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ycow [4]
3 years ago
6

The first-order rate constant for the decomposition of N2O5:

Chemistry
1 answer:
kifflom [539]3 years ago
5 0

Answer:

0.0055 mol of N2O5 will remay after 7 min.

Explanation:

The reaction follows a first-order.

Let the concentration of N2O5 after 7 min be y

Rate = Ky = change in concentration of N2O5/time

K is rate constant = 6.82×10^-3 s^-1

Initial concentration of N2O5 = number of moles/volume = 2.1×10^-2/1.8 = 0.0117 M

Change in concentration = 0.0117 - y

Time = 7 min = 7×60 = 420 s

6.82×10^-3y = 0.0117 - y/420

0.0117 - y = 420×6.82×10^-3y

0.0117 - y = 2.8644y

0.0117 = 2.8644y + y

0.0117 = 3.8644y

y = 0.0117/3.8644 = 0.00303 M

Number of moles of N2O5 left = y × volume = 0.00303 × 1.8 = 0.0055 mol (to 2 significant digits)

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Answer : The value of \Delta H_{vap} is 28.97 kJ/mol

Explanation :

To calculate \Delta H_{vap} of the reaction, we use clausius claypron equation, which is:

\ln(\frac{P_2}{P_1})=\frac{\Delta H_{vap}}{R}[\frac{1}{T_1}-\frac{1}{T_2}]

where,

P_1 = vapor pressure at temperature -21.0^oC = 462.7 mmHg

P_2 = vapor pressure at temperature -44.0^oC = 140.5 mmHg

\Delta H_{vap} = Enthalpy of vaporization = ?

R = Gas constant = 8.314 J/mol K

T_1 = initial temperature = -21.0^oC=[-21.0+273]K=252K

T_2 = final temperature = 45^oC=[-41.0+273]K=232K

Putting values in above equation, we get:

\ln(\frac{140.5mmHg}{462.7mmHg})=\frac{\Delta H_{vap}}{8.314J/mol.K}[\frac{1}{252}-\frac{1}{232}]\\\\\Delta H_{vap}=28966.6J/mol=28.97kJ/mol

Therefore, the value of \Delta H_{vap} is 28.97 kJ/mol

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Answer:

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