The sample with the lowest AVERAGE kinetic energy is
the coolest one.
The sample with the lowest TOTAL kinetic energy depends on
not only the temperature of the samples, but also on their size,
since each molecule in the sample has kinetic energy.
Answer:
The reaction is not spontaneous in the forward direction, but in the reverse direction.
Explanation:
<u>Step 1: </u>Data given
H2(g) + I2(g) ⇌ 2HI(g) ΔG° = 2.60 kJ/mol
Temperature = 25°C = 25+273 = 298 Kelvin
The initial pressures are:
pH2 = 3.10 atm
pI2 = 1.5 atm
pHI 1.75 atm
<u>Step 2</u>: Calculate ΔG
ΔG = ΔG° + RTln Q
with ΔG° = 2.60 kJ/mol
with R = 8.3145 J/K*mol
with T = 298 Kelvin
Q = the reaction quotient → has the same expression as equilibrium constant → in this case Kp = [p(HI)]²/ [p(H2)] [p(I2)]
with pH2 = 3.10 atm
pI2 = 1.5 atm
pHI 1.75 atm
Q = (3.10²)/(1.5*1.75)
Q = 3.661
ΔG = ΔG° + RTln Q
ΔG = 2600 J/mol + 8.3145 J/K*mol * 298 K * ln(3.661)
ΔG =5815.43 J/mol = 5.815 kJ/mol
To be spontaneous, ΔG should be <0.
ΔG >>0 so the reaction is not spontaneous in the forward direction, but in the reverse direction.
Answer:
212.5 mL
both the original and the diluted solution have 0.765 moles of KCl
Explanation:
c1V1 = c2V2
V2 = c1V1/c2 = (1.8 M×425 mL)/1.2 M = 637.5 mL
(637.5 - 425) mL = 212.5 mL
n = (1.8 mol/L)(0.425 L) = 0.765 moles of KCl
since it's a dilution, the diluted solution has the same number of moles as the original solution, 0.765 moles of KCl
Answer:
109° 27'
Explanation:
The ammonium ion is tetrahedral in shape, all the HNH bonds are exactly at the tetrahedral bond angle since there are only bond pairs in the structure and no lone pairs. Recall that lone pairs decrease the bond angke from the ideal value in a tetrahedron due to higher repulsion.
