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Yuri [45]
3 years ago
11

When a 1.0 M solution of HCl is titrated with a 1.0 M solution of KOH, which is the approximate pH at the equivalent point?

Chemistry
1 answer:
klio [65]3 years ago
4 0
The equivalence point is when the concentration of H⁺ in solution is equal to the concentration of OH⁻ in solution.  Since H⁺ and OH⁻ react with each other to make water (H⁺(aq)+OH⁻(aq)→H₂O(l)) the pH at the equivalence point is 7 due to everything being neutralized.  (The equivalence point only has a pH of 7 when a strong acid is being titrated with a strong base).

I hope this helps.  Let me know if anything is unclear.  
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The volume of the sample after the reaction takes place is 19.78 L.

Explanation:

The given variables are;

Number of moles of NH₃(g) = 0.1700 mol

Number of moles of O₂(g) = 0.2125 mol

Volume occupied by the mixture = 17.8 L

The reaction

4NH₃(g) + 5O₂(g) → 4NO(g) + 6H₂O(g)

Then takes place

That is 4 moles of NH₃(g) reacts with 5 moles of O₂(g) to produce 4 moles of NO(g) and 6 moles of H₂O(g).

Since there are less number of moles of NH₃(g) (= 0.1700 mol) in the mixture, we factor the above equation by the number of moles of NH₃(g)  present.

That is,

1 moles of NH₃(g) reacts with 5/4 moles of O₂(g) to produce 1 moles of NO(g) and 3/2 moles of H₂O(g).

Therefore,

0.1700 mol of NH₃(g) reacts with 5/4×0.1700  moles of O₂(g) to produce 0.1700  moles of NO(g) and 3/2×0.1700  moles of H₂O(g).

Which gives

0.1700 mol of NH₃(g) reacts with 0.2125  moles of O₂(g) to produce 0.1700  moles of NO(g) and 0.255  moles of H₂O(g).

Therefore, all of the NH₃(g) and O₂(g)  are consumed in the reaction and the present gases in sample then becomes

0.1700  moles of NO(g) and 0.255  moles of H₂O(g).

Total number of moles of reactant = 0.17 + 0.2125 = 0.3825

Total number of moles of product formed = 0.17 + 0.255 = 0.425

However, Avogadro's law states that equal volume of all gases at the same temperature and pressure contains equal number of molecules.

That is volume occupied by  0.3825 moles of gas = 17.8 L

Therefore the volume occupied by  0.425 moles of gas = 17.8×0.425/0.3825 L = 19.78 L

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3 years ago
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