3. The density of acetic anhydride is 1.08 g/mL. How many moles of acetic anhydride are used in this experiment
1 answer:
You might be interested in
Explanation :
As we know that the Gibbs free energy is not only function of temperature and pressure but also amount of each substance in the system.
where,
is the amount of component 1 and 2 in the system.
Partial molar Gibbs free energy : The partial derivative of Gibbs free energy with respect to amount of component (i) of a mixture when other variable are kept constant are known as partial molar Gibbs free energy of
component.
For a substance in a mixture, the chemical potential is defined as the partial molar Gibbs free energy.
The expression will be:
where,
T = temperature
P = pressure
is the amount of component 'i' and 'j' in the system.
Answer:
The correct answer is B.
Explanation:
Heterogeneous equilibrium is that in which reagents and products are present in more than one phase.
When the reaction is carried out in a closed container, three equilibrium phases are present: solid magnesium oxide, solid magnesium sulfate and gaseous sulfur trioxide.
Hence, the equilibrium contant is given by:
The concentrations in the equilibrium equation are the relationships of the real concentrations between the concentrations in the standard state. Since the standard state of a pure solid is the pure solid itself, the ratio of concentrations for a pure solid is equal to one.
Now, we analyse each statement:
I) As the reaction is endothermic (ΔH>0), increasing the temperature shifts the balance to the right because excess heat will be used to form more products.
II) Increasing the volume will decrease the concentration of SO₃, so Q>K and then this shifts the balance to the left.
III) As it is a heterogeneous balance, adding MgO will not affect the balance.
IV) Removing SO3 will decrease its concentration and therefore the reaction equilibrium will shift to the left.