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3 years ago

List common properties of bonds

Chemistry

1 answer:

konstantin123 [22]3 years ago

6 0

Answer:

Bond are the strong forces that holds two atoms Together in a molecule.

Explanation:

Some properties of bonds are as follow:

1. There are three types of bonds : ionic , covalent , coordinate

2. Ionic bonds are formed by transfer of electron form one atom to other. These bonds are very strong because they are formed by electrostatic force of attraction between opposite charges.

The ionic Bonds have very high lattice energy.

due to ionic bond , ionic compound have very high melting point ,boiling point, conductivity in melt state etc.

3. Covalent bonds : These bonds are formed by the sharing of electron .They are weaker than ionic bonds. The melting point and electrical conductivity of covalent compounds are lower than ionic bonds.

Why do elements combine to form bond?

They do so to get stability in order to complete their octet.

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Use the data given below to construct a Born-Haber cycle to determine the second ionization energy of Ca. Δ H°(kJ) Ca(s)→Ca(g) 1

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Answer : The value of second ionization energy of Ca is 1010 kJ.

Explanation :

The formation of calcium oxide is,

$Ca(s)+\frac{1}{2}O_2(g)\overset{\Delta H_f}\rightarrow CaO(s)$

$\Delta H_f^o$ = enthalpy of formation of calcium oxide = -635 kJ

The steps involved in the born-Haber cycle for the formation of $CaO$ :

(1) Conversion of solid calcium into gaseous calcium atoms.

$Ca(s)\overset{\Delta H_s}\rightarrow Ca(g)$

$\Delta H_s$ = sublimation energy of calcium = 193 kJ

(2) Conversion of gaseous calcium atoms into gaseous calcium ions.

$Ca(g)\overset{\Delta H_I_1}\rightarrow Ca^{+1}(g)$

$\Delta H_I_1$ = first ionization energy of calcium = 590 kJ

(3) Conversion of gaseous calcium ion into gaseous calcium ions.

$Ca^{+1}(g)\overset{\Delta H_I_2}\rightarrow Ca^{+2}(g)$

$\Delta H_I_2$ = second ionization energy of calcium = ?

(4) Conversion of molecular gaseous oxygen into gaseous oxygen atoms.

$O_2(g)\overset{\Delta H_D}\rightarrow OI(g)$

$\frac{1}{2}O_2(g)\overset{\Delta H_D}\rightarrow O(g)$

$\Delta H_D$ = dissociation energy of oxygen = $\frac{498}{2}=249kJ$

(5) Conversion of gaseous oxygen atoms into gaseous oxygen ions.

$O(g)\overset{\Delta H_E_1}\rightarrow O^-(g)$

$\Delta H_E_1$ = first electron affinity energy of oxygen = -141 kJ

(6) Conversion of gaseous oxygen ion into gaseous oxygen ions.

$O^-(g)\overset{\Delta H_E_2}\rightarrow O^{2-}(g)$

$\Delta H_E_2$ = second electron affinity energy of oxygen = 878 kJ

(7) Conversion of gaseous cations and gaseous anion into solid calcium oxide.

$Ca^{2+}(g)+O^{2-}(g)\overset{\Delta H_L}\rightarrow CaO(s)$

$\Delta H_L$ = lattice energy of calcium oxide = -3414 kJ

To calculate the overall energy from the born-Haber cycle, the equation used will be:

$\Delta H_f^o=\Delta H_s+\Delta H_I_1+\Delta H_I_2+\Delta H_D+\Delta H_E_1+\Delta H_E_2+\Delta H_L$

Now put all the given values in this equation, we get:

$-635kJ=193kJ+590kJ+\Delta H_I_2+249kJ+(-141kJ)+878kJ+(-3414kJ)$

$\Delta H_I_2=1010kJ$

Therefore, the value of second ionization energy of Ca is 1010 kJ.

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