Answer:
Activation energy of phenylalanine-proline peptide is 66 kJ/mol.
Explanation:
According to Arrhenius equation-
, where k is rate constant, A is pre-exponential factor,
is activation energy, R is gas constant and T is temperature in kelvin scale.
As A is identical for both peptide therefore-
![\frac{k_{ala-pro}}{k_{phe-pro}}=e^\frac{[E_{a}^{phe-pro}-E_{a}^{ala-pro}]}{RT}](https://tex.z-dn.net/?f=%5Cfrac%7Bk_%7Bala-pro%7D%7D%7Bk_%7Bphe-pro%7D%7D%3De%5E%5Cfrac%7B%5BE_%7Ba%7D%5E%7Bphe-pro%7D-E_%7Ba%7D%5E%7Bala-pro%7D%5D%7D%7BRT%7D)
Here
, T = 298 K , R = 8.314 J/(mol.K) and 
So, ![\frac{0.05}{0.005}=e^{\frac{[E_{a}^{phe-pro}-(60000J/mol)]}{8.314J.mol^{-1}.K^{-1}\times 298K}}](https://tex.z-dn.net/?f=%5Cfrac%7B0.05%7D%7B0.005%7D%3De%5E%7B%5Cfrac%7B%5BE_%7Ba%7D%5E%7Bphe-pro%7D-%2860000J%2Fmol%29%5D%7D%7B8.314J.mol%5E%7B-1%7D.K%5E%7B-1%7D%5Ctimes%20298K%7D%7D)
(rounded off to two significant digit)
So, activation energy of phenylalanine-proline peptide is 66 kJ/mol
Answer:
Solutions are always homogeneous.
Explanation:
Solution:
Solution are considered homogeneous because in solution the ratio of solute and solvent remain the same throughout the solution. Both solute and solvent are chemically combined and form a new substance.
In solution the particles of solute can not be seen through naked eye.
When the light is passed through the solution it can not scattered.
Example:
When salt is dissolve in water it makes a solution.
The solution also exist in gaseous form. For example oxygen and many other gases dissolved in nitrogen also form a solution.
Mixture:
In mixture substance are physically combined. In mixture every every individual particle retain their properties.
It can be consist of solid, liquid and gas.
Examples:
Sand in water is also a mixture.
Oil in water form mixture.
True !! size dependent properties state is only one of the many physical properties of matter some physical properties such as massive value depending on the size or the amount measures of these properties very depending on how much matter is in a sample.
5.5 moles
2.0=x/2.75
2.0*2.75= x/2.75 (2.75)
5.5=x
Answer:
CuSO4(aq) + 4NH3(aq) + nH2O→ [Cu(NH3)4H2On]S04(aq)
Explanation:
When the concentrated ammonia is added into the copper ions solution, a blue solid is formed. This blue solid is gelatinous.it consist of Cu(OH)2 in insoluble form. As more ammonia is added precipitate start to dissolve and [Cu(NH3)4]∧+2 is produce.
Net Ionic equation:
Cu∧+2 +4NH3 → [Cu(NH3)4]∧+2
S04∧-2 are spectator ions.
Properties and uses of Tetraaminecopper(ll) sulfate:
1. It is solid compound.
2. Its color is dark blue.
3. It has ammonia like odor.
4. It is used to make the copper compounds and also used in the printing of fabric.
5. It is also used as pesticide.