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Kamila [148]
3 years ago
12

Be sure to answer all parts. consider the combustion of butane gas: c4h10(g) + 13 2 o2(g) → 4co2(g) + 5h2o(g) (a) predict the si

gns of δs o and δh o . δs o : negative positive δh o : negative positive (b) calculate δg o at 298 k. kj
Chemistry
1 answer:
9966 [12]3 years ago
5 0
Answers are:
1) ΔH is negative because that is combustion reaction and heat is released, enthalpy of combustion is -2877.5 kJ/mol.
2) ΔS is positive, because there more molecules on the right side of balanced chemical reaction, standard molar entropy is <span>310.23 J/mol</span>·<span>K.
</span>3) ΔG = ΔH - TΔS.
ΔG = -2877.5 kJ/mol - 298 K · 310.23 J/mol·K.
ΔG = -2969.95 kJ/mol.
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Answer:

e) The activation energy of the reverse reaction is greater than that of the forward reaction.

Explanation:

  • Activation energy is the minimum amount of energy that is required by the reactants to start a reaction.
  • An exothermic reaction is a reaction that releases heat energy to the surrounding while an endothermic reactions is a reaction that absorbs heat from the surrounding.
  • <em><u>In reversible reactions, when the forward reaction is exothermic it means the reverse reaction will be endothermic, therefore the reverse reaction will have a higher activation energy than the forward reaction.</u></em> The activation energy of the reverse reaction will be the sum of the enthalpy and the activation energy of the forward reaction.
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Which solution when mixed with a drop of bromthymol blue will cause the indicator to change from blue to yellow 1) 0.1 M HCl. 2)
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4 years ago
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3 years ago
Two linear hydrocarbons, Hexane (C6H14) and Heptane (C7H16), form pretty much an ideal solution at any composition. A solution i
Anettt [7]

Answer:

y_{C_6H_{14}}=0.92

Explanation:

Hello,

At first, we compute liquid-phase molar fractions:

n_{C_6H_{14}}=463.96 g*\frac{1mol}{86g} =5.3949molC_6H_{14}\\n_{C_7H_{16}}=667.71 g*\frac{1mol}{100g} =6.6771molC_7H_{16}\\x_{C_6H_{14}}=\frac{5.3949}{5.3949+6.6771} =0.447\\x_{C_7H_{16}}=1-x_{C_6H_{14}}=0.553

Now, by means of the fugacity concept, for hexane, for instance, we have:

f_{C_6H_{14}}^V=f_{C_6H_{14}}^L\\y_{C_6H_{14}}p_T=x_{C_6H_{14}}p_{C_6H_{14}}

In this manner, at 25 °C the vapor pressure of hexane and heptane are 0.198946 atm and 0.013912 atm repectively, thus, the total pressure is:

p_T=x_{C_6H_{14}}p_{C_6H_{14}}+x_{C_7H_{16}}p_{C_7H_{16}}\\p_T=0.447*0.198946 atm +0.553*0.013912 atm=0.096622atm

Finally, from the hexane's fugacity equation, we find its mole fraction in the vapour as:

y_{C_6H_{14}}=\frac{x_{C_6H_{14}}p_{C_6H_{14}}}{p_T}=\frac{0.447*0.198946 atm}{0.096622atm} \\y_{C_6H_{14}}=0.92

Best regards.

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