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Ipatiy [6.2K]
3 years ago
13

A photon with a wavelength of less than 50.4 nm can ionize a helium atom.

Chemistry
1 answer:
attashe74 [19]3 years ago
7 0

Answer:

  • <em><u>4.38 × 10⁻³⁵ J</u></em>

Explanation:

The <em>ionization potential</em> is the energy required to separate an electron from an atom in gas state and, so, form an ion.

Since it is said that<em> a photon with wavelength of less than 50.4 nm can ionize a Helium atom</em>, the energy of such photon is the ionization potential (energy) of Helium.

The energy of a photon in terms of its wavelength is given by Planck - Einstein's equation:

  • E = h . f = h / (λ . c)

Where,

  • E is the energy of the photon,
  • λ is the wavelength,
  • f is the frequency,
  • h is the Planck's constant = 6.626 × 10⁻³⁴ J.s⁻¹
  • c is the speed of light ≈ 3.0 × 10 ⁸ m/s

Here you know the wavelength, λ = 50.4 nm. You must convert it to meter: 50.4 nm × 10 ⁻⁹ m.

Now you can substitute and compute:

  • E = h / (λ . c) = 6.626 × 10⁻³⁴ J.s⁻¹ / (50.4 × 10⁻⁹ m × 3.0 × 10 ⁸ m/s)

  • E = 0.0438 × 10⁻³³ J = 4.38 × 10⁻³⁵ J ← answer

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A certain first-order reaction 45% complete in 65seconds, determine the rate constant and the half life for the process ​
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The rate constant : k = 9.2 x 10⁻³ s⁻¹

The half life : t1/2 = 75.3 s

<h3>Further explanation</h3>

Given

Reaction 45% complete in 65 s

Required

The rate constant and the half life

Solution

For first order ln[A]=−kt+ln[A]o

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A = 0.55

Ao = 1

Input the value :

ln A = -kt + ln Ao

ln 0.55 = -k.65 + ln 1

-0.598=-k.65

k = 9.2 x 10⁻³ s⁻¹

The half life :

t1/2 = (ln 2) / k

t1/2 = 0.693 : 9.2 x 10⁻³

t1/2 = 75.3 s

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