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Vinvika [58]
3 years ago
14

Consider the following balanced equation for the dissociation of barium hydroxide in an aqueous solution.

-dn.net/?f=%5Csmall%20Ba%28OH%29_%7B2%7D_%7B%28s%29%7D%20%5Crightleftharpoons%20Ba%5E%7B2%2B%7D_%7B%28aq%29%7D%20%2B%202OH%5E%7B-%7D_%7B%28aq%29%7D" id="TexFormula1" title="\small Ba(OH)_{2}_{(s)} \rightleftharpoons Ba^{2+}_{(aq)} + 2OH^{-}_{(aq)}" alt="\small Ba(OH)_{2}_{(s)} \rightleftharpoons Ba^{2+}_{(aq)} + 2OH^{-}_{(aq)}" align="absmiddle" class="latex-formula">K_{sp} = 5 x 10⁻³A 1M solution of barium nitrate is added to the solution. What is the solubility of barium hydroxide after this addition?a. 0.035Mb. 0.108Mc. 0.050Md. 0.118Me. 0.003M
Chemistry
1 answer:
Stolb23 [73]3 years ago
4 0

Answer:

a. 0,035M

Explanation:

For the reaction:

Ba(OH)₂(s) ⇄ Ba²⁺(aq) + 2OH⁻(aq)

Ksp is defined as:

Ksp = [Ba²⁺] [OH⁻]²

5x10⁻³ = [Ba²⁺] [OH⁻]²

if is added a solution of 1M of Ba²⁺:

5x10⁻³ = [1M] [OH⁻]²

The addition of barium hydroxide Ba(OH)₂ gives:

[Ba²⁺] = 1M + x

[OH⁻]² = 2x

Replacing:

5x10⁻³ = [1 + x] [2x]²

5x10⁻³ = 4x² + 4x³

Solutions are:

x = -1,00 M

x = -0,036 M

<em><u>x = 0,035 M</u></em> → Right answer, there are not negative concentrations.

Thus, solubility is

<em>a. 0,035M</em>

<em></em>

I hope it helps!

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Answer:

102kPa

Explanation:

760mmHg = 101.325 kPa

12mmHg = x

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x = ( 12 mm Hg x  101.325 kPa)  / 760mmHg

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Total pressure = 100.8 kPa + 1.599868421 kPa

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What is the entropy change of the system when 17.5 g of liquid benzene (c6h6) evaporates at the normal boiling point? the normal
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can a light object that was hit with a small force accelerate as rapidly as a heavier object hit with a big force? why or why no
Tcecarenko [31]

The acceleration is defined by force divided by the mass of the object. So, When the smaller object is hit by a small force, it can produce equal acceleration which is same as that of the bigger body hit with large force.

<h3><u>Explanation:</u></h3>

Force is defined as the product of the mass of the body its applied to and the acceleration of the body in the direction of the force. So acceleration is force divided by the mass of the body.

Let the mass of the smaller body be m and that of the larger body be M.

The smaller force applied on the smaller body be f and the larger force applied on the larger body be F.

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3 years ago
Write the equilibrium constant expression for this reaction: 2H+(aq)+CO−23(aq) → H2CO3(aq)
MrRissso [65]

Answer:

Equilibrium constant expression for \rm 2\; H^{+}\, (aq) + {CO_3}^{2-}\, (aq) \rightleftharpoons H_2CO_3\, (aq):

\displaystyle K = \frac{\left(a_{\mathrm{H_2CO_3\, (aq)}}\right)}{\left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}}\right)} \approx \frac{[\mathrm{H_2CO_3}]}{\left[\mathrm{H^{+}\, (aq)}\right]^{2} \, \left[\mathrm{CO_3}^{2-}\right]}.

Where

  • a_{\mathrm{H_2CO_3}}, a_{\mathrm{H^{+}}}, and a_{\mathrm{CO_3}^{2-}} denote the activities of the three species, and
  • [\mathrm{H_2CO_3}], \left[\mathrm{H^{+}}\right], and \left[\mathrm{CO_3}^{2-}\right] denote the concentrations of the three species.

Explanation:

<h3>Equilibrium Constant Expression</h3>

The equilibrium constant expression of a (reversible) reaction takes the form a fraction.

Multiply the activity of each product of this reaction to get the numerator.\rm H_2CO_3\; (aq) is the only product of this reaction. Besides, its coefficient in the balanced reaction is one. Therefore, the numerator would simply be \left(a_{\mathrm{H_2CO_3\, (aq)}}\right).

Similarly, multiply the activity of each reactant of this reaction to obtain the denominator. Note the coefficient "2" on the product side of this reaction. \rm 2\; H^{+}\, (aq) + {CO_3}^{2-}\, (aq) is equivalent to \rm H^{+}\, (aq) + H^{+}\, (aq) + {CO_3}^{2-}\, (aq). The species \rm H^{+}\, (aq) appeared twice among the reactants. Therefore, its activity should also appear twice in the denominator:

\left(a_{\mathrm{H^{+}}}\right)\cdot \left(a_{\mathrm{H^{+}}}\right)\cdot \, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}})\right = \left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}})\right.

That's where the exponent "2" in this equilibrium constant expression came from.

Combine these two parts to obtain the equilibrium constant expression:

\displaystyle K = \frac{\left(a_{\mathrm{H_2CO_3\, (aq)}}\right)}{\left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}}\right)} \quad\begin{matrix}\leftarrow \text{from products} \\[0.5em] \leftarrow \text{from reactants}\end{matrix}.

<h3 /><h3>Equilibrium Constant of Concentration</h3>

In dilute solutions, the equilibrium constant expression can be approximated with the concentrations of the aqueous "(\rm aq)" species. Note that all the three species here are indeed aqueous. Hence, this equilibrium constant expression can be approximated as:

\displaystyle K = \frac{\left(a_{\mathrm{H_2CO_3\, (aq)}}\right)}{\left(a_{\mathrm{H^{+}}}\right)^2\, \left(a_{\mathrm{{CO_3}^{2-}\, (aq)}}\right)} \approx \frac{\left[\mathrm{H_2CO_3\, (aq)}\right]}{\left[\mathrm{H^{+}\, (aq)}\right]^2\cdot \left[\mathrm{{CO_3}^{2-}\, (aq)}\right]}.

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A pure substance always consists of a single element or compound. Example Oxygen is formed only of oxygen (O) atoms; whereas the table salt which is formed only by sodium chloride (NaCl) molecules is a compound which is made up of pure elements. A pure substance cannot be further divided into its components.

A mixture is made up of different compounds and/or elements. It can be easily separated using any physical method. Example, sand, salt and saw dust mixed together as a mixture. Also, it will not have a definite chemical formula.

Please refer the attachment for better understanding.

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