Which of the following does NOT involve a physical change?
1 answer:
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Vanillin is the common name for 4-hydroxy-3-methoxy-benzaldehyde.
See attached figure for the structure.
Vanillin have 3 functional groups:
1) aldehyde group: R-HC=O, in which the carbon is double bonded to oxygen
2) phenolic hydroxide group: R-OH, were the hydroxyl group is bounded to a carbon from the benzene ring
3) ether group: R-O-R, were hydrogen is bounded through sigma bonds to carbons
Now for the hybridization we have:
The carbon atoms involved in the benzene ring and the red carbon atom (from the aldehyde group) have a <u>sp²</u> hybridization because they are involved in double bonds.
The carbon atom from the methoxy group (R-O-CH₃) and the blue oxygen's have a <u>sp³</u> hybridization because they are involved only in single bonds.
Explanation:
Starting moles of ethanol acid = 0.020 mol
At the equilibrium 50 % of the ethanol acid molecules reacted
∴ Moles of ethanol acid reacted = 0.020 mol * 50 %/100 %
= 0.010 mol
Moles of ethanol acid remain = 0.020 mol + 0.010 mol = 0.010 mol
Moles of the product gas formed are calculated as
0.010 mol CH3COOH * 1 mol / 2 mol CH3COOH
= 0.005 mol
Therefore at the equilibrium total moles of gas present in the vessel are 0.010 mol CH3COOH and 0.005 mol
That is total gas moles at equilibrium = 0.010 mol + 0.005 mol = 0.015 mol
Now Calculate the pressure :
0.020 mol gas has pressure of 0.74 atm therefore at the same condition what will be the pressure exerted by 0.015 mol gas
P1/n1 = P2/n2
P2 = P1*n2 / n1
= 0.74 atm * 0.015 mol / 0.020 mol
= 0.555 atm