ethylene and steam at 320 celsius and 1 atm are fed to a reaction process as an equimolar mixture. the process produces ethanol
which leaves the process as liquid at 25 celcius. what is the heat transfer associated with the process per mole of ethanol produced
1 answer:
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Answer:
1.58x10⁻⁵
2.51x10⁻⁸
0.0126
63.10
Explanation:
Phenolphthalein acts like a weak acid, so in aqueous solution, it has an acid form HIn, and the conjugate base In-, and the pH of it can be calculated by the Handerson-Halsebach equation:
pH = pKa + log[In-]/[HIn]
pKa = -logKa, and Ka is the equilibrium constant of the dissociation of the acid. [X] is the concentrantion of X. Thus,
i) pH = 4.9
4.9 = 9.7 + log[In-]/[HIn]
log[In-]/[HIn] = - 4.8
[In-]/[HIn] =
[In-]/[HIn] = 1.58x10⁻⁵
ii) pH = 2.1
2.1 = 9.7 + log[In-]/[HIn]
log[In-]/[HIn] = -7.6
[In-]/[HIn] =
[In-]/[HIn] = 2.51x10⁻⁸
iii) pH = 7.8
7.8 = 9.7 + log[In-]/[HIn]
log[In-]/[HIn] = -1.9
[In-]/[HIn] =
[In-]/[HIn] = 0.0126
iv) pH = 11.5
11.5 = 9.7 + log[In-]/[HIn]
log[In-]/[HIn] = 1.8
[In-]/[HIn] =
[In-]/[HIn] = 63.10