Consider the halogenation of ethene is as follows:
CH₂=CH₂(g) + X₂(g) → H₂CX-CH₂X(g)
We can expect that this reaction occurring by breaking of a C=C bond and forming of two C-X bonds.
When bond break it is endothermic and when bond is formed it is exothermic.
So we can calculate the overall enthalpy change as a sum of the required bonds in the products:
Part a)
C=C break = +611 kJ
2 C-F formed = (2 * - 552) = -1104 kJ
Δ H = + 611 - 1104 = - 493 kJ
2C-Cl formed = (2 * -339) = - 678 kJ
ΔH = + 611 - 678 = -67 kJ
2 C-Br formed = (2 * -280) = -560 kJ
ΔH = + 611 - 560 = + 51 kJ
2 C-I Formed = (2 * -209) = -418 kJ
ΔH = + 611 - 418 = + 193 kJ
Part b)
As we can see that the highest exothermic bond formed is C-F bond so from bond energies we can found that addition of fluoride is the most exothermic reaction
The answer is protons and electrons! Hope this helps :D
Answer:
Kc = 50.5
Explanation:
We determine the reaction:
H₂ + I₂ ⇄ 2HI
Initially we have 0.001 molesof H₂
and 0.002 moles of I₂
If we have produced 0.00187 moles of HI in the equilibrium we have to know, how many moles of I₂ and H₂, have reacted.
H₂ + I₂ ⇄ 2HI
In: 0.001 0.002 -
R: x x 2x
Eq: 0.001-x 0.002-x 0.00187
x = 0.00187/2 = 9.35×10⁻⁴ moles that have reacted
So in the equilibrium we have:
0.001 - 9.35×10⁻⁴ = 6.5×10⁻⁵ moles of H₂
0.002 - 9.35×10⁻⁴ = 1.065×10⁻³ moles of I₂
Expression for Kc is = (HI)² / (H₂) . (I₂)
0.00187 ² / 6.5×10⁻⁵ . 1.065×10⁻³ = 50.5
Answer:
The correct answer is "Fragment B likely has a higher Guanosine/Citosine content".
Explanation:
Guanosine/Citosine content, or GC content, refers to how many molecules of guanosine and citosine have a DNA fragment, respect to the content of adenine and thymine. The higher the GC content, the higher the temperature needed to denature the fragment of DNA. This happens because guanosine and citosine establish three hydrogen bonds, while adenine and thymine establish two hydrogen bonds when they bind together. Therefore, if fragment A and B are the same length, but at 89 C only fragment A is completely denatured, fragment B likely has a higher GC content.
