9) After lab, all of Darrel’s friends looked at his data and laughed and laughed. They told him that he was 30.8% too low in the
2 answers:
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Explanation:
Sodium hydroxide completely ionizes in water to produce sodium ions and hydroxide ions. Hydroxide ions are in excess and neutralize all acetic acid added by the following ionic equation:
The mixture would contain
of
and
of
if undergoes no hydrolysis; the solution is of volume
after the mixing. The two species would thus be of concentration
and
, respectively.
Construct a RICE table for the hydrolysis of under a basic aqueous environment (with a negligible hydronium concentration.)
The question supplied the <em>acid</em> dissociation constant for acetic acid
; however, calculating the hydrolysis equilibrium taking place in this basic mixture requires the <em>base</em> dissociation constant
for its conjugate base,
. The following relationship relates the two quantities:
... where the water self-ionization constant under standard conditions. Thus
. By the definition of
:
Answer:
Explanation:
The reaction between dimethyl malonate which is an active methylene group with an (∝, β-unsaturated carbonyl compound) i.e methyl vinyl ketone is known as a Micheal Addition reaction. The reaction mechanism starts with the base attack on the β-carbon to remove the acidic ∝-hydrogens and form a carbanion. The carbanion formed(enolate ion) attacks the methyl vinyl ketone(i.e. a nucleophilic attack at the β-carbon) to give a Micheal addition product, this is followed by the protonation to give the neutral product.
