Answer:
4
Explanation:
Relationship between wavenumber and Rydberg constant (R) is as follows:

Here, Z is atomic number.
R=109677 cm^-1
Wavenumber is related with wavelength as follows:
wavenumber = 1/wavelength
wavelength = 253.4 nm

Z fro Be = 4

Therefore, the principal quantum number corresponding to the given emission is 4.
A metal rail rusting in damp weather.
Second law of thermodynamics states entropy of the universe is always increasing. entropy always increases in a spontaneous process .
option B) second law of thermodynamics
for example if we keep a hot cup of coffee the heat is lost to surrounding and entropy( randomness increases) since it is a natural process entropy of universe increases.