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luda_lava [24]
3 years ago
13

What is it about the structure of methyl alcohol that would result in two major peaks in its NMR spectrum?

Chemistry
1 answer:
UNO [17]3 years ago
6 0

Explanation:

In case of methyl alcohol , i.e. , CH₃OH ,

counting the equivalent protons , there are three protons of the methyl group at are all equivalent  , and shows the chemical shift at 3.4 - 4.0 ppm , there is the increase in the chemical shift value due to the presence of an electronegative oxygen atom .

And there is one more hydrogen atom in the alcoholic functional group , and this hydrogen will also show a chemical shift at 5.0 - 5.5 ppm .

Therefore ,

Methyl alcohol will show two signals due to methyl proton and another due to OH hydrogen .

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A 0.43g samle of KHP required 24.11cm of NaOH for neutralization. Calculate the molarity of NaOH
expeople1 [14]

Answer:

0.083 M

Explanation:

We'll begin by calculating the number of mole in 0.43 g of KHP (potassium hydrogen phthalate, C₈H₅O₄K). This is can be obtained as follow:

Mass of C₈H₅O₄K = 0.43 g

Molar mass of C₈H₅O₄K = (8×12) + (5×1) + (16× 4) + 39

= 96 + 5 + 64 + 39 = 204 g/mol

Mole of C₈H₅O₄K =?

Mole = mass / molar mass

Mole of C₈H₅O₄K = 0.43 / 204

Mole of C₈H₅O₄K = 0.002 mole

Next, we shall determine the number of mole of NaOH required to react with 0.43 g (i.e 0.002 mole) of KHP. This can be obtained as follow:

C₈H₅O₄K + NaOH → C₈H₄O₄KNa + H₂O

From the balanced equation above,

1 mole of KHP reacted with 1 mole of NaOH.

Therefore, 0.002 mole of KHP will also react with 0.002 mole of NaOH.

Next, we shall convert 24.11 cm³ to L. This can be obtained as follow:

1000 cm³ = 1 L

Therefore,

24.11 cm³ = 24.11 cm³ × 1 L / 1000 cm³

24.11 cm³ = 0.02411 L

Finally, we shall determine the molarity of NaOH. This can be obtained as follow:

Mole of NaOH = 0.00 2 mole

Volume = 0.02411 L

Molarity of NaOH =?

Molarity = mole /Volume

Molarity of NaOH = 0.002 / 0.02411

Molarity of NaOH = 0.083 M

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